A novel and highly stereoselective intramolecular formal [3+3] cycloaddition reaction of vinylogous amides tethered with α,β-unsaturated aldehydes:: A formal total synthesis of (+)-gephyrotoxin

被引：0

作者：

Wei, LL ^{[1
]}

Hsung, RP ^{[1
]}

Sklenicka, HM ^{[1
]}

Gerasyuto, AI ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 08期

关键词：

D O I：

10.1002/1521-3773(20010417)40:8<1516::AID-ANIE1516>3.0.CO;2-V

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complex piperidinyl heterocycles (for example, 2) were accessed by using a novel intramolecular formal [3+3] cycloaddition reaction of vinylogous amides tethered with enals (for example, 1). This method has been applied to a formal total sythesis of (+)-gephyrotoxin (3).

引用

页码：1516 / +

页数：4

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