Time-Dependent Stokes Shift from Solvent Dielectric Relaxation

被引：0

作者：

Xu, Jing ^{[2
]}

Wang, Quan-de ^{[2
]}

Zhu, Quan ^{[1
]}

Fu, Ke-xiang ^{[1
]}

He, Fu-cheng ^{[1
]}

Li, Xiang-yuan ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem Engn, Chengdu 610065, Peoples R China

[2] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China

来源：

CHINESE JOURNAL OF CHEMICAL PHYSICS | 2010年 / 23卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Stokes shift; Solvation energy; Characteristic time; NONEQUILIBRIUM POLARIZATION SYSTEMS; CAVITY MODEL FRCM; SOLVATION DYNAMICS; ELECTRON-TRANSFER; POLAR SOLVATION; FREE-ENERGY; REORGANIZATION ENERGY; TREATING EQUILIBRIUM; OPTICAL-CONSTANTS; CONTINUUM MODEL;

D O I：

10.1088/1674-0068/23/03/297-302

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The Stokes shift response function, which is related to the time dependent solvation energy, is calculated with the dielectric response function and a novel expression of nonequilibrium solvation energy. In the derivation, relationship between the polarization and the dielectric response function is used. With the dipole-in-a-sphere model applied to the system coumarin 343 and water as the solvent, encouraging agreement with the experimental data from Jimenez et al. is obtained [Nature 369, 471 (1994)].

引用

页码：297 / 302

页数：6

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