Generation of metallosupramolecular polymer gels from multiply functionalized grid-type complexes

被引：17

作者：

Hardy, John George ^{[1
]}

Cao, Xiao-yu ^{[1
]}

Harrowfield, Jack ^{[1
]}

Lehn, Jean-Marie ^{[1
]}

机构：

[1] Univ Strasbourg, ISIS, Lab Chim Supramol, F-67083 Strasbourg, France

来源：

NEW JOURNAL OF CHEMISTRY | 2012年 / 36卷 / 03期

关键词：

PHOSPHORUS-CONTAINING AMPHIPHILES; SUPRAMOLECULAR POLYMERS; LUMINESCENCE PROPERTIES; MAGNETIC-PROPERTIES; PHASE MATERIALS; REDOX BEHAVIOR; DENDRITIC GEL; FT-IR; ORGANOGELS; GELATORS;

D O I：

10.1039/c2nj20898a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A ditopic ligand (1), containing two tridentate bis(acylhydrazone) subunits and bearing both long alkyl chains and hydrogen-bonding groups, has been synthesised. Metal cation binding in the presence of a base leads to hierarchical self-assembly, forming first a neutral [2 x 2] grid-type complex (2) that hierarchically assembles into metallosupramolecular polymer gels in toluene.

引用

页码：668 / 673

页数：6

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