Generation of metallosupramolecular polymer gels from multiply functionalized grid-type complexes

被引：17
|
作者：
Hardy, John George [1 ]
Cao, Xiao-yu [1 ]
Harrowfield, Jack [1 ]
Lehn, Jean-Marie [1 ]
机构：
[1] Univ Strasbourg, ISIS, Lab Chim Supramol, F-67083 Strasbourg, France
来源：
NEW JOURNAL OF CHEMISTRY | 2012年 / 36卷 / 03期
关键词：
PHOSPHORUS-CONTAINING AMPHIPHILES; SUPRAMOLECULAR POLYMERS; LUMINESCENCE PROPERTIES; MAGNETIC-PROPERTIES; PHASE MATERIALS; REDOX BEHAVIOR; DENDRITIC GEL; FT-IR; ORGANOGELS; GELATORS;
D O I：
10.1039/c2nj20898a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A ditopic ligand (1), containing two tridentate bis(acylhydrazone) subunits and bearing both long alkyl chains and hydrogen-bonding groups, has been synthesised. Metal cation binding in the presence of a base leads to hierarchical self-assembly, forming first a neutral [2 x 2] grid-type complex (2) that hierarchically assembles into metallosupramolecular polymer gels in toluene.
引用
收藏
页码：668 / 673
页数：6
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