Mechanochemical sulfonation of aromatic compounds using NaHSO4•H2O/P2O5

被引：1
|
作者：
Zuo, Lu-Lu [1 ]
Qin, Shuai [1 ]
Zhang, Pu [1 ]
Qin, Yu-Jun [1 ]
Guo, Zhi-Xin [1 ]
机构：
[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2021年 / 45卷 / 11-12期
关键词：
aromatic compounds; mechanochemical; NaHSO4; H2O; P2O5; sulfonation; SULFUR-TRIOXIDE; ACIDS; PARAMETERS; OXIDATION; KINETICS; THIOLS; C-60;
D O I：
10.1177/17475198211032571
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of aromatic sulfonic acids is synthesized by subjecting arenes and NaHSO4 center dot H2O to high-speed ball milling in the presence of P2O5. It is suggested the aromatic sulfonation occurs via in situ generated H2SO4 to give aromatic sulfonic acids. In some cases, formation of diaryl sulfones was observed.
引用
收藏
页码：942 / 949
页数：8
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