Fluorimetric determination of bromoform via its photochemical reaction with diphenylamine in aqueous Triton X-100 medium

被引：0

作者：

Pal, A ^{[1
]}

Bandyopadhyay, M ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Civil Engn, Kharagpur 721302, W Bengal, India

来源：

INDIAN JOURNAL OF CHEMICAL TECHNOLOGY | 2001年 / 8卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new fluorimetric method based on the photochemical reaction of CHBr3 with diphenylamine (DPA) in aqueous Triton X-100 (TX-100) medium is described for the determination of bromoform (CHBr3). The fluorescence intensity of the product at 480nm (lambda ex: 400nm) is a direct measure of CHBr3 concentration. The calibration graph is linear in the range of 0-21.8 ppm of CHBr3. The limit of detection (LOD) is 0.1 ppm of CHBr3. The effect of reagent concentration, TX-100 concentration, time of irradiation, interfering substances, and statistical parameters are discussed.

引用

页码：83 / 87

页数：5

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