Synthesis of Dihydrophosphaisocoumarins through a Palladium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with 1,3-Dienes

被引：21
|
作者：
Son, Jeong-Yu [1 ]
Kim, Hyunseok [1 ]
Jeon, Woo Hyung [1 ]
Baek, Yonghyeon [1 ]
Seo, Boram [1 ]
Um, Kyusik [1 ]
Lee, Kooyeon [2 ]
Lee, Phil Ho [1 ]
机构：
[1] Kangwon Natl Univ, Dept Chem, Chunchon 24341, South Korea
[2] Kangwon Natl Univ, Dept Bio Hlth Technol, Chunchon 24341, South Korea
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2017年 / 359卷 / 18期
基金：
新加坡国家研究基金会;
关键词：
catalysis; C-H activation; cyclization; palladium; phosphaheterocycles; BOND-CLEAVAGE; PHOSPHAISOCOUMARINS; ACTIVATION; AZOBENZENES; MONOESTERS; DERIVATIVES; PHOSPHATES; AMIDATION; LIGANDS;
D O I：
10.1002/adsc.201700742
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
An efficient synthetic method for the selective preparation of dihydrophosphaisocoumarins and their derivatives was developed through a palladium-catalyzed oxidative cyclization reaction of a wide range of arylphosphonic acid monoethyl esters with activated and unactivated 1,3-dienes, including 1-aryl-substituted 1,3-dienes and 1-alkyl-substituted 1,3-dienes, thus opening a new avenue for the synthesis of phosphaheterocyclic compounds.
引用
收藏
页码：3194 / 3206
页数：13
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