Synthesis of Dihydrophosphaisocoumarins through a Palladium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with 1,3-Dienes

被引：21

作者：

Son, Jeong-Yu ^{[1
]}

Kim, Hyunseok ^{[1
]}

Jeon, Woo Hyung ^{[1
]}

Baek, Yonghyeon ^{[1
]}

Seo, Boram ^{[1
]}

Um, Kyusik ^{[1
]}

Lee, Kooyeon ^{[2
]}

Lee, Phil Ho ^{[1
]}

机构：

[1] Kangwon Natl Univ, Dept Chem, Chunchon 24341, South Korea

[2] Kangwon Natl Univ, Dept Bio Hlth Technol, Chunchon 24341, South Korea

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2017年 / 359卷 / 18期

基金：

新加坡国家研究基金会;

关键词：

catalysis; C-H activation; cyclization; palladium; phosphaheterocycles; BOND-CLEAVAGE; PHOSPHAISOCOUMARINS; ACTIVATION; AZOBENZENES; MONOESTERS; DERIVATIVES; PHOSPHATES; AMIDATION; LIGANDS;

D O I：

10.1002/adsc.201700742

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An efficient synthetic method for the selective preparation of dihydrophosphaisocoumarins and their derivatives was developed through a palladium-catalyzed oxidative cyclization reaction of a wide range of arylphosphonic acid monoethyl esters with activated and unactivated 1,3-dienes, including 1-aryl-substituted 1,3-dienes and 1-alkyl-substituted 1,3-dienes, thus opening a new avenue for the synthesis of phosphaheterocyclic compounds.

引用

页码：3194 / 3206

页数：13

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