Synthesis of dihydrofuroflavonoids via palladium-catalyzed annulation of 1,3-dienes

被引:16
|
作者
Rozhkov, RV [1 ]
Larock, RC [1 ]
机构
[1] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA
关键词
palladium catalyzed; dihydrofuroflavone; flavone; isoflavone; flavanone; flavonoid; 1,3-diene;
D O I
10.1016/j.tetlet.2003.11.114
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The palladium-catalyzed annulation of 1,3-dienes by o-iodoacetoxyflavonoids provides an efficient approach to biologically interesting dihydrofuroflavonoids. This reaction is very general, regioselective, and a wide variety of terminal, cyclic, and internal 1,3-dienes can be utilized. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:911 / 914
页数:4
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