Indium sulfide thin films deposited by chemical spray of aqueous and alcoholic solutions

被引：27

作者：

Otto, K. ^{[1
]}

Katerski, A. ^{[1
]}

Volobujeva, O. ^{[1
]}

Mere, A. ^{[1
]}

Krunks, M. ^{[1
]}

机构：

[1] Tallinn Univ Technol, Dept Mat Sci, EE-19086 Tallinn, Estonia

来源：

EMRS-C: MATERIALS DEVICES AND ECONOMICS ISSUES FOR TOMORROW'S PHOTOVOLTAICS | 2011年 / 3卷

关键词：

Indium sulfide; chemical spray pyrolysis; solvents; structural properties; morphology; elemental composition; XRD; SEM; XPS; PYROLYSIS;

D O I：

10.1016/j.egypro.2011.01.011

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In2S3 films were grown by pneumatic chemical spray method using aqueous and alcoholic solutions containing InCl3 and SC(NH2)(2) at molar ratios of [In]/[S]=1/3 and 1/6. Films were deposited onto preheated glass sheets in air at heater (molten Sn bath) temperatures of 250 and 330 degrees C. Films were characterized by means of XRD, SEM, UV-VIS spectra and XPS. beta-In2S3 films were formed independent of the technological variables. The films from aqueous solutions are highly orientated along (0 0 12) plane parallel to the substrate, with E-g of 2.2-2.3 eV (indirect transitions). Spray of alcoholic solutions results in thinner but more compact films with reduced (0 0 12) orientation, E-g of ca. 2.0 eV, and no chlorine contamination when deposited at 330 degrees C. According to XPS, the films have uniform concentration of the elements through the film thickness, spray of sulfur-rich solutions ([In]/[S]=1/6) results in the films with lower oxygen content. (C)2009 Published by Elsevier B. V.

引用

页数：7

共 50 条

[21] STRUCTURAL, OPTICAL, AND ELECTRICAL CHARACTERIZATION OF SPRAY PYROLYSED INDIUM SULFIDE THIN FILMS
Rahman, F.
Podder, J.
Ichimura, M.
SURFACE REVIEW AND LETTERS, 2013, 20 (02)
[22] Porous indium oxide thin films deposited by electrostatic spray deposition technique
Ghimbeu, Camelia Matei
Schoonman, Joop
Lumbreras, Martine
CERAMICS INTERNATIONAL, 2008, 34 (01) : 95 - 100
[23] Indium sulfide thin films as window layer in chemically deposited solar cells
Lugo-Loredo, S.
Pena-Mendez, Y.
Calixto-Rodriguez, M.
Messina-Fernandez, S.
Alvarez-Gallegos, A.
Vazquez-Dimas, A.
Hernandez-Garcia, T.
THIN SOLID FILMS, 2014, 550 : 110 - 113
[24] Indium Doped Zinc Oxide Thin Films Deposited by Ultrasonic Chemical Spray Technique, Starting from Zinc Acetylacetonate and Indium Chloride
Biswal, Rajesh
Maldonado, Arturo
Vega-Perez, Jaime
Roberto Acosta, Dwight
De La Luz Olvera, Maria
MATERIALS, 2014, 7 (07): : 5038 - 5046
[25] THE EFFECT OF DIFFERENT COMPLEXING AGENTS ON THE PROPERTIES OF ZINC SULFIDE THIN FILMS DEPOSITED FROM AQUEOUS SOLUTIONS
Shapova, Pavlo
Sozanskyi, Martyn
Yatchyshyn, Iosyp
Kulyk, Bogdan
Shpotyuk, Mykhaylo
Gladyshevskii, Roman
CHEMISTRY & CHEMICAL TECHNOLOGY, 2016, 10 (03): : 317 - 323
[26] Optoelectronical properties of indium sulfide thin films prepared by spray pyrolysis for photovoltaic applications
Calixto-Rodriguez, M
Tiburcio-Silver, A
Ortiz, A
Sanchez-Juarez, A
THIN SOLID FILMS, 2005, 480 : 133 - 137
[27] Tin doping in spray pyrolysed indium sulfide thin films for solar cell applications
Mathew, Meril
Gopinath, Manju
Kartha, C. Sudha
Vijayakumar, K. P.
Kashiwaba, Y.
Abe, T.
SOLAR ENERGY, 2010, 84 (06) : 888 - 897
[28] On tuning the preferential crystalline orientation of spray pyrolysis deposited indium oxide thin films
Attaf, A.
Bouhdjer, A.
Saidi, H.
Aida, M. S.
Attaf, N.
Ezzaouia, H.
THIN SOLID FILMS, 2017, 625 : 177 - 179
[29] Deposition and Characterization of CIGS Thin Films Deposited by Chemical Spray Process
Zhang, Yujie
Jun, Hoyoung
Park, Jae Young
Park, Seon Young
Ryu, Sang Ouk
Ryu, Si Ok
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2015, 617 (01) : 186 - 194
[30] Gallium-doped ZnO thin films deposited by chemical spray
Gomez, H
Maldonado, A
Olvera, MDLL
Acosta, DR
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 87 (1-4) : 107 - 116

← 1 2 3 4 5 →