Unusual coordination mode of tetradentate Schiff base cobalt(III) complexes

被引：32

作者：

Cyriac, Anish ^{[1
]}

Jeon, Jong Yeob ^{[1
]}

Varghese, Jobi Kodiyan ^{[1
]}

Park, Ji Hae ^{[1
]}

Choi, Soo Young ^{[2
]}

Chung, Young Keun ^{[2
]}

Lee, Bun Yeoul ^{[1
]}

机构：

[1] Ajou Univ, Dept Mol Sci & Technol, Suwon 443749, South Korea

[2] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 05期

关键词：

CO2/PROPYLENE OXIDE COPOLYMERIZATION; HYDROLYTIC KINETIC RESOLUTION; SALEN COMPLEXES; CARBON-DIOXIDE; ALTERNATING COPOLYMERIZATION; ASYMMETRIC CATALYSIS; CYCLOHEXENE OXIDE; TERMINAL EPOXIDES; EFFICIENT; LIGAND;

D O I：

10.1039/c2dt11871h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Contrary to the stereotype, Jacobsen's catalyst, chiral (salcy)Co(III)OAc adopts an unusual binding mode. The tetradentate {ONNO} ligand does not form a square plane but wraps cobalt in a cis-beta fashion while acetate is chelating.

引用

页码：1444 / 1447

页数：4

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