Unusual coordination mode of tetradentate Schiff base cobalt(III) complexes

被引：32

作者：

Cyriac, Anish ^{[1
]}

Jeon, Jong Yeob ^{[1
]}

Varghese, Jobi Kodiyan ^{[1
]}

Park, Ji Hae ^{[1
]}

Choi, Soo Young ^{[2
]}

Chung, Young Keun ^{[2
]}

Lee, Bun Yeoul ^{[1
]}

机构：

[1] Ajou Univ, Dept Mol Sci & Technol, Suwon 443749, South Korea

[2] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 05期

关键词：

CO2/PROPYLENE OXIDE COPOLYMERIZATION; HYDROLYTIC KINETIC RESOLUTION; SALEN COMPLEXES; CARBON-DIOXIDE; ALTERNATING COPOLYMERIZATION; ASYMMETRIC CATALYSIS; CYCLOHEXENE OXIDE; TERMINAL EPOXIDES; EFFICIENT; LIGAND;

D O I：

10.1039/c2dt11871h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Contrary to the stereotype, Jacobsen's catalyst, chiral (salcy)Co(III)OAc adopts an unusual binding mode. The tetradentate {ONNO} ligand does not form a square plane but wraps cobalt in a cis-beta fashion while acetate is chelating.

引用

页码：1444 / 1447

页数：4

共 50 条

[21] Synthesis, characterization, and spectroscopic studies of tetradentate Schiff base chromium(III) complexes
Aranha, Pedro E.
dos Santos, Mirian P.
Romera, Sandra
Dockal, Edward R.
POLYHEDRON, 2007, 26 (07) : 1373 - 1382
[22] PREPARATION AND ELECTROCHEMICAL STUDIES OF TETRADENTATE MANGANESE(III) SCHIFF-BASE COMPLEXES
BOGGESS, RK
HUGHES, JW
COLEMAN, WM
TAYLOR, LT
INORGANICA CHIMICA ACTA-ARTICLES, 1980, 38 (02): : 183 - 189
[23] Tetradentate Schiff base oxovanadium(IV) complexes
Zamian, JR
Dockal, ER
TRANSITION METAL CHEMISTRY, 1996, 21 (04) : 370 - 376
[24] The thermodynamics of tertiary phosphine cobalt (III) Schiff base complexes
Asadi, M
Sarvestani, AH
Hemateenejad, B
JOURNAL OF CHEMICAL RESEARCH-S, 2002, (10): : 520 - 523
[25] Thermodynamics of Cobalt(III) Schiff base complexes in various solvents
M. Asadi
M. Setoodeh Khah
A. H. Kianfar
Journal of the Iranian Chemical Society, 2010, 7 : 38 - 44
[26] Tetradentate Schiff base copper(II) complexes
Felicio, RC
da Silva, GA
Ceridorio, LF
Dockal, ER
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1999, 29 (02): : 171 - 192
[27] Synthesis, spectroscopy and electrochemistry of cobalt(III) Schiff base complexes
Sarvestani, AH
Salimi, A
Mohebbi, S
Hallaj, R
JOURNAL OF CHEMICAL RESEARCH-S, 2005, (03): : 190 - 193
[28] TETRADENTATE SCHIFF BASE COMPLEXES OF LEAD(IV)
BIRADAR, NS
KULKARNI, VH
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1971, 381 (03): : 312 - &
[29] Thermodynamics of Cobalt(III) Schiff Base Complexes in Various Solvents
Asadi, M.
Khah, M. Setoodeh
Kianfar, A. H.
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2010, 7 (01) : 38 - 44
[30] COBALT(III) COMPLEXES OF POLYDENTATE SCHIFF-BASE LIGANDS
BURNESS, JH
DILLARD, JG
TAYLOR, LT
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1976, 6 (03): : 165 - 177

← 1 2 3 4 5 →