The first (31P, 17O, and 103Rh) NMR observation complex formation of rhodium(III) with phosphoric acid

被引：4

作者：

Fedotov, M. A. ^{[1
]}

Belyaev, A. V. ^{[2
]}

机构：

[1] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 53卷 / 05期

关键词：

D O I：

10.1134/S0036023608050148

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(31)P, (17)O, and (103)Rh NMR spectroscopy shows that rhodium(III) reacts with phosphoric acid to generate polynuclear aquaphosphate complexes in which phosphate ions mostly have a bridging function. Assignment of (103)Rh NMR signals in dominant rhodium complexes is suggested.

引用

页码：761 / 764

页数：4

共 38 条

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