The first (31P, 17O, and 103Rh) NMR observation complex formation of rhodium(III) with phosphoric acid

被引：4
|
作者：
Fedotov, M. A. [1 ]
Belyaev, A. V. [2 ]
机构：
[1] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 53卷 / 05期
关键词：
D O I：
10.1134/S0036023608050148
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
(31)P, (17)O, and (103)Rh NMR spectroscopy shows that rhodium(III) reacts with phosphoric acid to generate polynuclear aquaphosphate complexes in which phosphate ions mostly have a bridging function. Assignment of (103)Rh NMR signals in dominant rhodium complexes is suggested.
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页码：761 / 764
页数：4
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