(η6-Arene)tricarbonylchromium and (η5-cyclohexadienyl)tricarbonylmanganese complexes:: indirect nucleophilic substitutions

被引：72
|
作者：
Rose-Munch, F [1 ]
Gagliardini, V [1 ]
Renard, C [1 ]
Rose, E [1 ]
机构：
[1] Univ Paris 06, UMR CNRS 761 1, Lab Synthese Organ & Organomet, F-75252 Paris 05, France
来源：
COORDINATION CHEMISTRY REVIEWS | 1998年 / 178卷
关键词：
arene; arene complexes; aromatic substitution; benzenetricarbonylchromium; benzenetricarbonylmanganese; nucleophilic substitution;
D O I：
10.1016/S0010-8545(98)00078-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of X-substituted (eta(6)-arene) tricarbonylchromium complexes with a nucleophile and a proton source afforded new arenetricarbonylchromium complexes via chromium hydride intermediates and elimination of HX (cine and tele nucleophilic aromatic substitutions). Treatment of (eta(5)-X-substituted-cyclohexadienyl)tricarbonyl manganese complexes with hydride and a proton source gave eta(5)-cyclohexadienyl complexes resulting from a cleavage of the C-X bond: the eta(3)-X-substituted cyclohexenyl intermediates underwent elimination of an agostic hydrogen and the X group. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：249 / 268
页数：20
相关论文
共 50 条
  • [41] Distorted (η6-arene)tricarbonylchromium complexes:: Correlation of structural parameters with the electronegativity χG and Hammett constants σp of arene substituents
    Djukic, JP
    Rose-Munch, F
    Rose, E
    Vaissermann, J
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, (06) : 1295 - 1306
  • [42] Thermal decomposition of homo- and heterometallic (η6-arene)tricarbonylchromium derivatives
    Gomes, ELS
    Casagrande, OL
    THERMOCHIMICA ACTA, 1999, 331 (01) : 87 - 91
  • [43] Functionalised η6-arene ruthenium complexes
    Therrien, Bruno
    COORDINATION CHEMISTRY REVIEWS, 2009, 253 (3-4) : 493 - 519
  • [44] Arene Ring Expansion by Ruthenium η6-Arene Complexes
    Whitehurst, William G.
    Schulte, Tim
    Wang, Zikuan
    Waldbach, Felix
    Ritter, Tobias
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2025, 64 (06)
  • [45] Mesomorphic (eta(6)-arene)tricarbonylchromium complexes
    Campillos, E
    Deschenaux, R
    Levelut, AM
    Ziessel, R
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (12): : 2533 - 2536
  • [46] (ETA-6-ARENE)TRICARBONYLCHROMIUM COMPLEXES
    MAHAFFY, CAL
    PAUSON, PL
    INORGANIC SYNTHESES, 1990, 28 : 136 - 147
  • [47] Chemistry of unsaturated arenetricarbonylchromium compounds 1. Reaction of (η6-arene)tricarbonylchromium complexes of nitrones with methyl phenylpropiolate
    Zarovkina, N. Yu.
    Sazonova, E. V.
    Artemov, A. N.
    Fukin, G. K.
    RUSSIAN CHEMICAL BULLETIN, 2014, 63 (04) : 970 - 975
  • [48] Chemistry of unsaturated arenetricarbonylchromium compounds 1. Reaction of (η6-arene)tricarbonylchromium complexes of nitrones with methyl phenylpropiolate
    N. Yu. Zarovkina
    E. V. Sazonova
    A. N. Artemov
    G. K. Fukin
    Russian Chemical Bulletin, 2014, 63 : 970 - 975
  • [49] Application of (η6-arene) chromium tricarbonyl complexes in organic synthesis:: Nucleophilic aromatic substitution and lithiation
    Rose-Munch, F
    Rose, E
    CURRENT ORGANIC CHEMISTRY, 1999, 3 (05) : 445 - 467
  • [50] Ruthenium-coordinated spirolactams via intramolecular nucleophilic addition to η6-arene metal complexes
    Pigge, FC
    Coniglio, JJ
    Fang, SY
    ORGANOMETALLICS, 2002, 21 (21) : 4505 - 4512
12345