Electrochemically promoted decarboxylative borylation of alkyl N-hydroxyphthalimide esters

被引：27
|
作者：
Dai, Jian-Jun [1 ,2 ]
Teng, Xin-Xin [1 ]
Fang, Wen [1 ]
Xu, Jun [1 ,2 ]
Xu, Hua-Jian [1 ,2 ]
机构：
[1] Hefei Univ Technol, Sch Food & Biol Engn, Hefei 230009, Peoples R China
[2] Hefei Univ Technol, Anhui Prov Key Lab Adv Catalyt Mat & React Engn, Hefei 230009, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2022年 / 33卷 / 03期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
Electrochemical; Decarboxylation; Borylation; Alkyl boronic esters; Redox active esters; IRON-CATALYZED BORYLATION; ORGANIC ELECTROSYNTHESIS; ALKYLBORONIC ESTERS; RADICAL BORYLATION; COUPLING REACTIONS; HALIDES; SECONDARY; HYDROBORATIONS; METHODOLOGY; REAGENTS;
D O I：
10.1016/j.cclet.2021.09.011
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal- or photo-catalysts. The key feature of the reaction is the compatibility of diboron reagents with the electrochemical conditions. This reaction exhibits broad substrate scope, good functional group tolerability, and easy scalability. (C) 2021 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
引用
收藏
页码：1555 / 1558
页数：4
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