Chiral Diene as the Ligand for the Synthesis of Axially Chiral Compounds via Palladium-Catalyzed Suzuki-Miyaura Coupling Reaction

被引：105

作者：

Zhang, Shu-Sheng ^{[1
]}

Wang, Zhi-Qian ^{[1
]}

Xu, Ming-Hua ^{[1
,2
]}

Lin, Guo-Qiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 23期

关键词：

METAL-OLEFIN BOND; ASYMMETRIC ARYLATION; CONJUGATE ADDITION; 1,4-ADDITION; COMPLEXES; DESIGN; ACIDS;

D O I：

10.1021/ol102521q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first palladium-diene-catalyzed asymmetric Suzuki-Miyaura coupling reaction has been achieved. A number of functionalized biaryls were obtained in high yields and in moderate to high enantioselectivities. The existence of an ortho-formyl group greatly improves the catalyst efficiency and permits further synthetic elaborations.

引用

页码：5546 / 5549

页数：4

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