An efficient protocol for palladium-catalyzed ligand-free Suzuki-Miyaura coupling in water

被引：136
|
作者：
Mondal, Manoj [1 ]
Bora, Utpal [1 ]
机构：
[1] Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India
来源：
GREEN CHEMISTRY | 2012年 / 14卷 / 07期
关键词：
AMPHIPHILIC RESIN; AQUEOUS-MEDIA; ORGANOBORANES; PALLADACYCLES; NANOPARTICLES; MICROWAVE; SUPPORTS; POLYMER; COMPLEX; SILICA;
D O I：
10.1039/c2gc35401b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An in situ generated catalytic system based on PdCl2 and sodium sulfate exhibited excellent catalytic activity in the Suzuki-Miyaura cross-coupling reactions of aryl halides with arylboronic acids at room temperature in water. A similar catalytic system can be obtained with PdCl2 and sodium chloride or sodium acetate and is equally effective in Suzuki-Miyaura cross-coupling reactions. This method offers a mild and efficient alternative to the existing protocols since the reaction is proceeded in water at room temperature under ligand free conditions.
引用
收藏
页码：1873 / 1876
页数：4
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