Spectral and Luminescent Properties of Atropisomers of 5,10,15,20-Tetrakis(3-N-Methylpyridyl)Porphyrin in Aqueous Solutions

被引：2
|
作者：
Liulkovich, L. S. [1 ,2 ]
Pukhovskay, S. G. [1 ,3 ]
Ivanova, Yu. B. [4 ]
Gladkov, L. L. [5 ]
Kruk, M. M. [1 ]
机构：
[1] Belarusian State Technol Univ, 13a Sverdlov Str, Minsk 220006, BELARUS
[2] RUE Belmedpreparaty, Minsk 220007, BELARUS
[3] Ivanovo State Univ Chem & Technol, Ivanovo 153000, Russia
[4] Russian Acad Sci, GA Krestov Inst Solut Chem, Ivanovo 153045, Russia
[5] Belarusian State Acad Commun, 8-2 F Skorina Str, Minsk 220114, BELARUS
来源：
JOURNAL OF APPLIED SPECTROSCOPY | 2020年 / 86卷 / 06期
关键词：
porphyrins; atropisomer; absorption spectrum; fluorescence spectrum; molecular structure; WATER-SOLUBLE PORPHYRINS; CATIONIC PORPHYRINS;
D O I：
10.1007/s10812-020-00933-3
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Spectral and luminescent properties of aqueous solutions of 5,10,15,20-tetrakis(3-N-methylpyridyl)porphyrin are studied at 290 +/- 2 K. Individual absorption and fluorescence spectra are identified for atropisomers resulting from different orientations of the methylated N atom of the Py substituents relative to the mean plane of the tetrapyrrole macrocycle.
引用
收藏
页码：1014 / 1020
页数：7
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