Carboxylic Acid Promoted, Redox-Neutral Ru-Catalyzed C-H Allylation of Aromatic Ketones

被引：2
|
作者：
Dethe, Dattatraya H. [1 ]
Beeralingappa, Nagabhushana C. [1 ]
Dherange, Balu D. [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 2021卷 / 33期
关键词：
1-Adamantane carboxylic acid; Allylation; Aromatic ketones; Ketone directed reactions; Ruthenium; FRIEDEL-CRAFTS ALKYLATION; DIRECT ARYLATIONS; ALLYLIC ACETATES; BOND ALLYLATION; ARYL; FUNCTIONALIZATION; ACTIVATION; HALIDES; ARENES; ALKENES;
D O I：
10.1002/ejoc.202100717
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A redox-neutral, carboxylic acid promoted, [RuCl2(p-cymene)](2) catalyzed, weakly coordinating, carbonyl assisted C-H allylation of aromatic ketones has been developed. The beneficial effect of carboxylic acid on the ruthenium catalyst towards C-H allylation of aromatic ketones has been further explored, using commercially available allyl acetate under mild reaction conditions. In addition, this method requires redox-neutral reaction conditions, easily accessible starting materials, and shows excellent functional group compatibility.
引用
收藏
页码：4611 / 4615
页数：5
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