Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product

被引：1

作者：

Du, DM ^{[1
]}

Xue, F ^{[1
]}

Wong, HNC ^{[1
]}

Mak, TCW ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, New Territories, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1998年 / 28卷 / 11期

关键词：

2-methylnaphthalene; hexachlorocyclopentadiene; crystal structure;

D O I：

10.1023/A:1021819518557

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

2-Methylnaphthalene undergoes Diels-Alder addition and substitution with hexachlorocyclopentadiene to give two products, 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10-methyl-1,4;5,8-dimethanotriphenylene 1 and 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10-(1',2',3',4',5'-pentachlorocyclopentadienyl)methyl-1,4;5,8-dimethanotriphenylene 2. The molecular structure of 2 has been characterized by X-ray crystallography: C26H9Cl17, monoclinic, space group P2(1)/c, with a = 15.316(3), b = 13.698(3), c = 16.116(3) Angstrom, beta = 96.113(3)degrees, and Z = 4.

引用

页码：787 / 790

页数：4

共 50 条

[31] NEW ADDITION REACTION OF PHENYL ISO(THIO)CYANATE WITH CLEAVAGE PRODUCT OF GLYME
赵世开
马兆兰
邹多秀
曾宪谋
顾以健
ScienceBulletin, 1985, (05) : 706 - 707
[32] Identification and characterization of a reaction product of 2′-deoxyoxanosine with glycine
Suzuki, T
Yamada, M
Ide, H
Kanaori, K
Tajima, K
Morii, T
Makino, K
CHEMICAL RESEARCH IN TOXICOLOGY, 2000, 13 (04) : 227 - 230
[33] Mechanistic studies on oxidative addition of aryl halides and triflates to Pd(BINAP)2 and structural characterization of the product from aryl triflate addition in the presence of amine
Alcazar-Roman, LM
Hartwig, JF
ORGANOMETALLICS, 2002, 21 (03) : 491 - 502
[34] Structural characterization of the tobramycin-piperacillin reaction product formed at pH 6.0
Pagano, Thomas G.
Gong, Yumin
Kong, Fangming
Tsao, Rushung
Fawzi, Mahdi
Zhu, Tianmin
JOURNAL OF ANTIBIOTICS, 2011, 64 (10): : 673 - 677
[35] Structural and magnetic variations in tetranuclear NiII clusters: the effect of the reaction solvent and ligand substitution on product identity
Perlepe, Panagiota S.
Athanasopoulou, Angeliki A.
Alexopoulou, Konstantina I.
Raptopoulou, Catherine P.
Psycharis, Vassilis
Escuer, Albert
Perlepes, Spyros P.
Stamatatos, Theocharis C.
DALTON TRANSACTIONS, 2014, 43 (44) : 16605 - 16609
[36] Structural Characterization of Reaction Product Region in Al/MgO and Al/MgAl2O4 Systems
Nowak, Rafal
Sobczak, Natalia
Sienicki, Edmund
Morgiel, Jerzy
SOLID-SOLID PHASE TRANSFORMATIONS IN INORGANIC MATERIALS, PTS 1-2, 2011, 172-174 : 1273 - +
[37] CHARACTERIZATION OF ANTISERA TO THE ADDITION PRODUCT FORMED BY THE NONENZYMATIC REACTION OF 16-ALPHA-HYDROXYESTRONE WITH ALBUMIN
BUCALA, R
CERAMI, A
MOLECULAR IMMUNOLOGY, 1983, 20 (12) : 1289 - 1292
[38] Palladium catalysed addition substitution reaction of pronucleophiles with allenylstannane's and prop-2-ynylstannanes
Yamamoto, Y
AlMasum, M
Fujiwara, N
CHEMICAL COMMUNICATIONS, 1996, (03) : 381 - 382
[39] SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF RHCL2(PME2PH)2(C3PH3), THE PRODUCT OF AN OXIDATIVE ADDITION-LIGAND ELIMINATION-REACTION
FRISCH, PD
KHARE, GP
INORGANIC CHEMISTRY, 1979, 18 (03) : 781 - 786
[40] Molecular structure, polarizability, hyperpolarizability analysis and spectroscopic characterization of 1-(chloromethyl)-2-methylnaphthalene with experimental (FT-IR and FT-Raman) techniques and quantum chemical calculations
Nagabalasubramanian, P. B.
Karabacak, M.
Periandy, S.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 85 (01) : 43 - 52

← 1 2 3 4 5 →