Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product

被引：1

作者：

Du, DM ^{[1
]}

Xue, F ^{[1
]}

Wong, HNC ^{[1
]}

Mak, TCW ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, New Territories, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1998年 / 28卷 / 11期

关键词：

2-methylnaphthalene; hexachlorocyclopentadiene; crystal structure;

D O I：

10.1023/A:1021819518557

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

2-Methylnaphthalene undergoes Diels-Alder addition and substitution with hexachlorocyclopentadiene to give two products, 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10-methyl-1,4;5,8-dimethanotriphenylene 1 and 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10-(1',2',3',4',5'-pentachlorocyclopentadienyl)methyl-1,4;5,8-dimethanotriphenylene 2. The molecular structure of 2 has been characterized by X-ray crystallography: C26H9Cl17, monoclinic, space group P2(1)/c, with a = 15.316(3), b = 13.698(3), c = 16.116(3) Angstrom, beta = 96.113(3)degrees, and Z = 4.

引用

页码：787 / 790

页数：4

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