Pd-Catalyzed Diastereo- and Enantioselective [3+2]-Cycloaddition Reaction of Vinyl Epoxide with Nitroalkenes

被引：43

作者：

Wu, Wen-Qiong ^{[1
]}

Ding, Chang-Hua ^{[2
]}

Hou, Xue-Long ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

SYNLETT | 2012年 / 07期

基金：

中国国家自然科学基金;

关键词：

vinyl epoxide; nitroalkene; palladium; asymmetric catalysis; 3+2] cycloaddition; ASYMMETRIC CYCLOADDITION REACTIONS; SATURATED OXYGEN HETEROCYCLES; ACTIVATED OLEFINS; HECK REACTION; CASCADE REACTIONS; LIGANDS; TETRAHYDROFURANS; VINYLAZIRIDINES; CYCLOPROPANES; DERIVATIVES;

D O I：

10.1055/s-0031-1290525

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A diastereoselective and enantioselective [3+2]-cycloaddition reaction of vinyl epoxide and nitroalkenes has been developed using Pd/1,1'-ferrocene-P, N-ligand, providing substituted tetrahydrofurans in high yields and with high diastereo- and enantioselectivities.

引用

页码：1035 / 1038

页数：4

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