Self-assembly of a Cu(II)-Ba(II) 2D coordination polymer containing decanuclear 28-membered metallocycles

被引：9
|
作者：
Liu, WL [1 ]
Zou, Y [1 ]
Lu, CS [1 ]
Ni, CL [1 ]
Dang, DB [1 ]
Li, YZ [1 ]
Meng, QJ [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 03期
基金：
中国国家自然科学基金;
关键词：
metalloligand; heterometallic macrocycle; copper-barium; dipeptide; crystal structure;
D O I：
10.1016/j.inoche.2004.01.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel heterometallic 2D coordination polymer, {[Ba(H2O)(4)(CuL)(2)]}(infinity) (1) (H3L = N-2-hydroxyacetophenoneglycylglycine), was synthesized by self-assembly between metalloligands [CuL](-) and the Ba(II) ions. The structure reveals the polymer contains hexanuclear building blocks, which are connected to form 28-membered decanuclear metallocycles, and are assembled further into 2D network structure. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：434 / 436
页数：3
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