Self-assembly of a chiral three-dimensional manganese(II)-copper(II) coordination polymer with a double helical architecture

被引：16

作者：

Grancha, Thais ^{[1
]}

Tourbillon, Clarisse ^{[1
]}

Ferrando-Soria, Jesus ^{[2
]}

Julve, Miguel ^{[1
]}

Lloret, Francesc ^{[1
]}

Pasan, Jorge ^{[3
,4
]}

Ruiz-Perez, Catalina ^{[3
,4
]}

Fabelo, Oscar ^{[3
,4
,5
]}

Pardo, Emilio ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol ICMOL, Dept Quim Inorgan, Valencia 46980, Spain

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[3] Univ La Laguna, Lab Rayos 10, Tenerife 38201, Spain

[4] Univ La Laguna, Depto Fis Fundamental 2, Tenerife 38201, Spain

[5] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 45期

关键词：

DESIGN;

D O I：

10.1039/c3ce41022f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of the anionic dicopper(II) complex, [Cu-II(mpba)(2)](4-) [mpba = N,N'-1,3-phenylenebis(oxamate)], as tetrakis(bidentate) metalloligand toward Mn-II ions in the presence of oxalate and the chiral (S)-trimethyl-(1-phenylethyl)ammonium cation affords the first example of a mixed oxalato/oxamato-based chiral 3D metal-organic polymer.

引用

页码：9312 / 9315

页数：4

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