Fluorogenic Recognition of Zn2+, Al3+ and F- Ions by a New Multi-Analyte Chemosensor Based Bisphenol A-Quinoline

被引：28
|
作者：
Erdemir, Serkan [1 ]
Kocyigit, Ozcan [1 ]
Malkondu, Sait [1 ]
机构：
[1] Selcuk Univ, Dept Chem, Fac Sci, TR-42031 Konya, Turkey
来源：
JOURNAL OF FLUORESCENCE | 2015年 / 25卷 / 03期
关键词：
Bisphenol A; Quinoline; Fluorometric; Turn on; Chemosensor; FLUORESCENT SENSOR; NANOMOLAR DETECTION; HYDROGEN-SULFIDE; DRINKING-WATER; FLUORIDE IONS; ZINC; ALUMINUM; PROBE; TRIPHENYLAMINE; SELECTIVITY;
D O I：
10.1007/s10895-015-1557-6
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
A new available multi-analyte fluorescent sensor based on a bisphenol A-quinoline conjugate (BFQ) was synthesized in two facile steps and was characterized systematically. BFQ exhibited an effectively selective and sensitive recognition toward Zn(2+)and Al3+ cations in EtOH-H2O (v/v = 9/1) over other cations and F- anion in CH3CN over other anions with remarkably enhanced fluorescent intensities. According to the quantum yield (I broken vertical bar) measurements, BFQ-Zn2+, BFQ-Al3+ and BFQ-F- complexes showed 16, 22 and 30 times higher I broken vertical bar values than BFQ, respectively. The complexation properties of BFQ with Zn2+, Al3+ and F- ions were also examined by H-1 NMR titration experiments.
引用
收藏
页码：719 / 727
页数：9
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