Fluorogenic Recognition of Zn2+, Al3+ and F- Ions by a New Multi-Analyte Chemosensor Based Bisphenol A-Quinoline

被引：28

作者：

Erdemir, Serkan ^{[1
]}

Kocyigit, Ozcan ^{[1
]}

Malkondu, Sait ^{[1
]}

机构：

[1] Selcuk Univ, Dept Chem, Fac Sci, TR-42031 Konya, Turkey

来源：

JOURNAL OF FLUORESCENCE | 2015年 / 25卷 / 03期

关键词：

Bisphenol A; Quinoline; Fluorometric; Turn on; Chemosensor; FLUORESCENT SENSOR; NANOMOLAR DETECTION; HYDROGEN-SULFIDE; DRINKING-WATER; FLUORIDE IONS; ZINC; ALUMINUM; PROBE; TRIPHENYLAMINE; SELECTIVITY;

D O I：

10.1007/s10895-015-1557-6

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A new available multi-analyte fluorescent sensor based on a bisphenol A-quinoline conjugate (BFQ) was synthesized in two facile steps and was characterized systematically. BFQ exhibited an effectively selective and sensitive recognition toward Zn(2+)and Al3+ cations in EtOH-H2O (v/v = 9/1) over other cations and F- anion in CH3CN over other anions with remarkably enhanced fluorescent intensities. According to the quantum yield (I broken vertical bar) measurements, BFQ-Zn2+, BFQ-Al3+ and BFQ-F- complexes showed 16, 22 and 30 times higher I broken vertical bar values than BFQ, respectively. The complexation properties of BFQ with Zn2+, Al3+ and F- ions were also examined by H-1 NMR titration experiments.

引用

页码：719 / 727

页数：9

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