Syntheses and molecular structures of η3-[(η5-Cp*)(CO)2Fe-AsPC(SiMe3)2]M(CO)2(η5-Cp) (M = Mo,W):: the first complexes featuring η3-arsaphosphaallyl ligands

被引：7

作者：

Weber, L ^{[1
]}

Bayer, P ^{[1
]}

Stammler, HG ^{[1
]}

Neumann, B ^{[1
]}

机构：

[1] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 12期

关键词：

D O I：

10.1039/b414621b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of (eta(5)-Cp)(CO)(2)M=P=C(SiMe3)(2) 4a (M = Mo) and 4b (M=W) with (eta(5)- Cp*)(CO)(2)Fe -As=C(NMe2)(2) 5 affords the eta(3)- 1- arsa- 2- phosphaallyl complexes [(eta(5)- Cp*)(CO)(2)Fe AsPC( SiMe3)(2)] M(CO)(2)(eta(5)-Cp) 6a and 6b, the molecular structures of which were determined by X-ray analyses.

引用

页码：1595 / 1597

页数：3

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