Synthesis and structures of crystalline lithium 1-azaallyls and a 1,3-diazaallyl derived from Li{CH(SiMe3)(SiMe3-n(OMe)n)}(n=1 or 2) and Li{CH(SiMe2OMe)2} and RCN (R = tBu, Ph, 2,5-Me2C6H3, or Ad)

被引：15
|
作者：
Hitchcock, PB [1 ]
Lappert, MF [1 ]
Wei, XH [1 ]
机构：
[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 683卷 / 01期
关键词：
lithium; silylmethyls; 1-azaallyls; enamides; 1,3-diazaallyls; x-ray structures;
D O I：
10.1016/S0022-328X(03)00433-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
引用
收藏
页码：83 / 91
页数：9
相关论文
共 50 条
  • [21] ALKYLATION OF (AS, SB, BI)CL3 - FORMATION OF [(AS, SB, BI)RCL2], (E)-[BIR(CH2CH=C)(SIME3)(C5H4N-2)] AND 2-CH(SIME3)2C5H4N-5-R [R = C(SIME3)2C5H4N-2]
    JONES, C
    ENGELHARDT, LM
    JUNK, PC
    HUTCHINGS, DS
    PATALINGHUG, WC
    RASTON, CL
    WHITE, AH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (21) : 1560 - 1562
  • [22] Synthesis and structures of tin(II) and lead(II) 1-aza-allyls;: the [N(SiMe3)C(Ph)C(SiMe3)2]- ligand
    Hitchcock, PB
    Lappert, MF
    Layh, M
    [J]. INORGANICA CHIMICA ACTA, 1998, 269 (01) : 181 - 190
  • [23] Reaction of the silylene Si[(NCH2But) 2C6H4-1,2] with the alkali metal silylamides M[N(SiMe3)R] (M = Li, Na or K; R = SiMe3 or SiMe2Ph)
    Antolini, F
    Gehrhus, B
    Hitchcock, PB
    Lappert, MF
    Slootweg, JC
    [J]. DALTON TRANSACTIONS, 2004, (20) : 3288 - 3294
  • [24] Reactivity of Group 10 halides toward (Ph2PN=)C(Ph)[N(SiMe3)(2)], (NC5H4){(Ph2PN=)C[N(SiMe3)(2)]}-4 and C6H4{C(=NPPh2)[N(SiMe3)(2)]}(2)-1,4
    Wong, WK
    Sun, C
    Wong, WT
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (18): : 3387 - 3395
  • [25] Synthesis and characterization of Ta2(m-OMe)2(=NSiMe3)2[N(SiMe3)2]2Me2
    Chen, Shu-Jian
    Hunter, Seth C.
    Xue, Zi-ling
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [26] Syntheses of some bulky alkylalanes and alkyltrihydroaluminates:: crystal structures of [Li(THF)2AlH3C(SiMe3)2(SiMe2NMe2)]2, Li(THF)2Al2H5{C(SiMe3)3}2, (Me3Si)3CAlH2•THF and the pyrazolato derivative [LiAlH(C3H3N2)2C(SiMe3)3]2 (THF = tetrahydrofuran)
    Eaborn, C
    El-Hamruni, SM
    Hill, MS
    Hitchcock, PB
    Hopman, M
    Le Gouic, A
    Smith, JD
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 597 (1-2) : 3 - 9
  • [27] Synthesis and structural characterization of a novel asymmetric distannene [{1-[N(But)C(SiMe3)C(H)]-2-[N(But)(SiMe3)CC(H)]C6H4}Sn→Sn{1,2-[N(But)(SiMe3)CC(H)]2C6H4}]
    Leung, WP
    Cheng, H
    Huang, BR
    Yang, QC
    Mak, TCW
    [J]. CHEMICAL COMMUNICATIONS, 2000, (06) : 451 - 452
  • [28] Novel (silylimino)diarylphosphoranyl(trimethylsilyl)methyl-C,N ligands [CH(SiMe3)PPh2=NSiMe3](-) ([LL'](-)) and [CH(SiMe3){Ph(1,2-C6H4)P=NSiMe2}](-) ([LL''](-)) and the structures of [Li(LL'')](2) and [Pb(LL')(2)]
    Hitchcock, PB
    Lappert, MF
    Wang, ZX
    [J]. CHEMICAL COMMUNICATIONS, 1997, (12) : 1113 - 1114
  • [29] The diverse reactions of the silylene Si[(NCH2But)2C6H4-1,2] with Li[Si(SiMe3)3](thf)3 and K[N(SiMe3)2]
    Gehrhus, B
    Hitchcock, PB
    Lappert, MF
    Slootweg, JC
    [J]. CHEMICAL COMMUNICATIONS, 2000, (15) : 1427 - 1428
  • [30] Magnesium(II) Complexes of 2,4-N,N′-Disubstituted 1,3,5-Triazapentadienyl Ligands: Synthesis and Characterization of [N(Dipp)C(NMe2)NC(NMe2)N(SiMe3)MgBr]2 and [N(R)C(R′)NC(R′)N(SiMe3)]2Mg (Dipp=2,6-′Pr2-C6H3, R = Ph, SiMe3; R′ = NMe2, 1-piperidino)
    Zhou, Meisu
    Gong, Tao
    Qiao, Xiaoli
    Tong, Hongbo
    Guo, Jianping
    Liu, Diansheng
    [J]. INORGANIC CHEMISTRY, 2011, 50 (05) : 1926 - 1930
12345