ALKYLATION OF (AS, SB, BI)CL3 - FORMATION OF [(AS, SB, BI)RCL2], (E)-[BIR(CH2CH=C)(SIME3)(C5H4N-2)] AND 2-CH(SIME3)2C5H4N-5-R [R = C(SIME3)2C5H4N-2]

被引：35

作者：

JONES, C

ENGELHARDT, LM

JUNK, PC

HUTCHINGS, DS

PATALINGHUG, WC

RASTON, CL

WHITE, AH

机构：

[1] GRIFFITH UNIV,DIV SCI & TECHNOL,NATHAN,QLD 4111,AUSTRALIA

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

[3] DELASALLE UNIV,DEPT CHEM,MANILA,PHILIPPINES

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 21期

关键词：

D O I：

10.1039/c39910001560

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monomeric alkyldichloro-antimony(III) and -bismuth(III) compounds [MRCl2], R = C(SiMe3)2C5H4N-2', and the thermally unstable arsenic(III) analogue are accessible from the appropriate group 15 trichloride and LiR in diethyl ether; treating BiCl3 with two and three equivalents of LiR in tetrahydrofuran (THF) yields (E)-[BiR(CH2CH = C)(SiMe3)(C5H4N-2)] where the C2 insertion-SiMe3 elimination fragment originates from THF, and the 'head-to-tail' alkyl coupled species, 2-CH(SiMe3)2C5H4N-5-R.

引用

页码：1560 / 1562

页数：3

共 50 条

[1] Synthesis and structural characterisation of nickel(II) alkyl complexes NiR2, [Ni(Cp)R]2 and a 'head-to-tail' coupled alkyl intermediate compound [NiR(Cl)(R-R)] [R = C(SiMe3)2C5H4N-2, CPh(SiMe3)C5H4N-2 or CH(SiMe3)C5H4N-2; Cp = η5-C5H5]
Leung, WP
Lee, HK
Zhou, ZY
Mak, TCW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 564 (1-2) : 193 - 200
[2] The first structurally characterised σ-bonded organonickel(I) compound.: Crystal structures of [Ni{C(SiMe3)2(SiMe2C5H4N-2)}(PPh3)], [Ni{C(SiMe3)(SiMe2C5H4N-2)(SiMe2O)}]2 and [Pd(μ-Cl){C(SiMe3)2(SiMe2C5H4N-2)}]2
Eaborn, C
Hill, MS
Hitchcock, PB
Smith, JD
[J]. CHEMICAL COMMUNICATIONS, 2000, (08) : 691 - 692
[3] Synthesis and structures of alkali metal amides derived from the ligands [N(SiMe2Ph)(SiMe3)]-, [N(tBu)(SiMe3)]-, [N(Ph)(2-C5H4N)]- and [N(2-C5H4N)2]-
Antolini, F
Hitchcock, PB
Khvostov, AV
Lappert, MF
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (18) : 3391 - 3400
[4] Compounds of germanium, tin, and lead containing the ligand C(SiMe3)2(SiMe2C5H4N-2)
Al-Juaid, SS
Avent, AG
Eaborn, C
Hill, MS
Hitchcock, PB
Patel, DJ
Smith, JD
[J]. ORGANOMETALLICS, 2001, 20 (06) : 1223 - 1229
[5] Reactivity of Group 10 halides toward (Ph2PN=)C(Ph)[N(SiMe3)(2)], (NC5H4){(Ph2PN=)C[N(SiMe3)(2)]}-4 and C6H4{C(=NPPh2)[N(SiMe3)(2)]}(2)-1,4
Wong, WK
Sun, C
Wong, WT
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (18): : 3387 - 3395
[6] Organometallic compounds of Group 13 elements containing the ligand C(SiMe3)2(SiMe2C5H4N-2)
Howson, J
Eaborn, C
Hitchcock, PB
Hill, MS
Smith, JD
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (01) : 69 - 75
[7] AXIALLY ASYMMETRIC METAL ALKYLS .7. CRYSTALLOGRAPHIC CHARACTERIZATION OF LAMBDA-(R,R)-[ZR(2-CH(SIME3)C6H4)2(2-)(ETA-C5H5)2] AND DELTA-(S,S)-[ZR[2-CH(SIME3)C6H4]2(2-)(ETA-C5H5)2]
RASTON, CL
SKELTON, BW
TWISS, P
WHITE, AH
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1988, 41 (11) : 1773 - 1776
[8] BONDING INTERACTIONS BETWEEN 3 ADJACENT HYDROGEN LIGANDS - PREPARATION AND SPECTROSCOPIC PROPERTIES OF THE TANTALUM AND NIOBIUM COMPLEXES [TA(H)3(C5H5-NRN)2](R= SIME3, N = 1 OR 2) AND [NB(H3)(C5H5-NRN)2](N = 1, R = ME OR SIME3 - N = 2, R = SIME3)
ANTINOLO, A
CHAUDRET, B
COMMENGES, G
FAJARDO, M
JALON, F
MORRIS, RH
OTERO, A
SCHWELTZER, CT
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (17) : 1210 - 1212
[9] SYNTHESES AND CRYSTAL-STRUCTURES OF COMPLEXES [M2R2] [M = CU, AG, OR AU, R = 2-C(SIME3)2C5H4N] AND [CU42-CH(SIME3)C5H4N] - ELECTROCHEMICAL GENERATION OF [CU2R2]2+
PAPASERGIO, RI
RASTON, CL
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (12): : 3085 - 3091
[10] Alkyl alkyne mono((trimethylsilyl)cyclopentadienyl) niobium complexes.: Synthesis and chemical behavior in insertion processes.: X-ray crystal structures of [NbCp′(CH2SiMe3)2(Me3SiCCSiMe3)] and [NbCp′(NAr){η4-CH(SiMe3)C(SiMe3)C(CH2SiMe3)=CH(SiMe3)}],(Cp′=η5-C5H4SiMe3, Ar=2,6-Me2C6H3).: DFT studies of the model complexes [Nb(η5-C5H5)R2(HCCH)] (R = Cl, Me)
Galindo, A
Gómez, M
Gómez-Sal, P
Martín, A
del Río, D
Sánchez, F
[J]. ORGANOMETALLICS, 2002, 21 (02) : 293 - 304

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