Radiation curing of polyvinylsilane as a precursor for SiC-based material

被引：1
|
作者：
Idesaki, A
Sugimoto, M
Tanaka, S
Narisawa, M
Okamura, K
Itoh, M
机构：
[1] Japan Atom Energy Res Inst, Takasaki Radiat Chem Res Estab, Takasaki, Gumma 3701292, Japan
[2] Univ Osaka Prefecture, Grad Sch Engn, Dept Met & Mat Sci, Sakai, Osaka 5998531, Japan
[3] Fukushima Natl Coll Technol, Dept Chem & Biochem, Iwaki, Fukushima 9708034, Japan
来源：
ADVANCED CERAMICS AND COMPOSITES | 2003年 / 247卷
关键词：
polyvinylsilane; radiation curing; SiC;
D O I：
10.4028/www.scientific.net/KEM.247.129
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Irradiation effect of gamma-ray on polyvinylsilane (PVS) was investigated and the optimum curing condition to synthesize a minute SiC product with radiation curing was discussed. It was found that gases of hydrogen and ethylene were evolved by gamma-ray irradiation, and that there was no free radicals remained in the PVS after irradiation. A cured PVS maintaining its formed shape could be obtained by gamma-ray irradiation at room temperature under vacuum, and the cured PVS in solid state was obtained by irradiation with dose of above 3-4MGy.
引用
收藏
页码：129 / 132
页数：4
相关论文
共 50 条
  • [1] Ceramization process of polyvinylsilane as a precursor for SiC-based material
    A. Idesaki
    Y. Miwa
    Y. Katase
    M. Narisawa
    K. Okamura
    M. Itoh
    [J]. Journal of Materials Science, 2003, 38 : 2591 - 2596
  • [2] Ceramization process of polyvinylsilane as a precursor for SiC-based material
    Idesaki, A
    Miwa, Y
    Katase, Y
    Narisawa, M
    Okamura, K
    Itoh, M
    [J]. JOURNAL OF MATERIALS SCIENCE, 2003, 38 (12) : 2591 - 2596
  • [3] Synthesis of a minute SiC product from polyvinylsilane with radiation curing - Part I - Radiation curing of polyvinylsilane
    Idesaki, A
    Sugimoto, M
    Tanaka, S
    Narisawa, M
    Okamura, K
    Itoh, M
    [J]. JOURNAL OF MATERIALS SCIENCE, 2004, 39 (18) : 5689 - 5694
  • [4] Synthesis of a minute SiC product from polyvinylsilane with radiation curing Part I Radiation curing of polyvinylsilane
    A. Idesaki
    M. Sugimoto
    S. Tanaka
    M. Narisawa
    K. Okamura
    M. Itoh
    [J]. Journal of Materials Science, 2004, 39 : 5689 - 5694
  • [5] Synthesis of a minute SiC product from polyvinylsilane with radiation curing: Part II - Ceramization process of radiation cured polyvinylsilane
    Idesaki, Akira
    Sugimoto, Masaki
    Yoshikawa, Masahito
    Tanaka, Shigeru
    Narisawa, Masaki
    Okamura, Kiyohito
    Itoh, Masayoshi
    [J]. JOURNAL OF MATERIALS SCIENCE, 2007, 42 (01) : 130 - 135
  • [6] Synthesis of a minute SiC product from polyvinylsilane with radiation curing: Part II—Ceramization process of radiation cured polyvinylsilane
    Akira Idesaki
    Masaki Sugimoto
    Masahito Yoshikawa
    Shigeru Tanaka
    Masaki Narisawa
    Kiyohito Okamura
    Masayoshi Itoh
    [J]. Journal of Materials Science, 2007, 42 : 130 - 135
  • [7] CONVERSION MECHANISMS OF A POLYCARBOSILANE PRECURSOR INTO AN SIC-BASED CERAMIC MATERIAL
    BOUILLON, E
    LANGLAIS, F
    PAILLER, R
    NASLAIN, R
    CRUEGE, F
    HUONG, PV
    SARTHOU, JC
    DELPUECH, A
    LAFFON, C
    LAGARDE, P
    MONTHIOUX, M
    OBERLIN, A
    [J]. JOURNAL OF MATERIALS SCIENCE, 1991, 26 (05) : 1333 - 1345
  • [8] SiC-based fibers synthesized from hybrid polymer of polycarbosilane and polyvinylsilane
    Idesaki, A
    Narisawa, M
    Okamura, K
    Sugimoto, M
    Morita, Y
    Seguchi, T
    Itoh, M
    [J]. HIGH TEMPERATURE CERAMIC MATRIX COMPOSITES III, 1999, 164-1 : 39 - 42
  • [9] Synthesis of SiC-based fibers derived from hybrid polymer of polycarbosilane and polyvinylsilane
    Idesaki, A
    Narisawa, M
    Okamura, K
    Sugimoto, M
    Seguchi, T
    Itoh, M
    [J]. NOVEL SYNTHESIS AND PROCESSING OF CERAMICS, 1999, 159-1 : 107 - 111
  • [10] Radiation response of SiC-based fibers
    Youngblood, GE
    Jones, RH
    Kohyama, A
    Snead, LL
    [J]. JOURNAL OF NUCLEAR MATERIALS, 1998, 258 : 1551 - 1556
12345