Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands

被引：9

作者：

Zhang, Yu ^{[1
]}

Wang, Xinxin ^{[1
]}

Wang, Yaorong ^{[1
]}

Yuan, Dan ^{[1
]}

Yao, Yingming ^{[1
]}

机构：

[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Dushu Lake Campus, Suzhou 215123, Peoples R China

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 27期

基金：

中国国家自然科学基金;

关键词：

RING-OPENING POLYMERIZATION; AMINE BIS(PHENOLATE) LIGANDS; INTERMOLECULAR HYDROPHOSPHINATION; HYDROAMINATION REACTIONS; 1-HEXENE POLYMERIZATION; ALKALINE-EARTHS; RAC-LACTIDE; PRECATALYSTS; REACTIVITY; TITANIUM;

D O I：

10.1039/c8dt02122h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zirconium complexes stabilized by amine-bridged bis(phenolato) ligands showed good activity and chemo-selectivity in catalyzing intermolecular hydrophosphination of C-C multiple bonds with primary phosphines under mild conditions. A broad range of alkenes and alkynes underwent a mono-addition reaction with phenylphosphine, which generated secondary phosphines in 39-99% yields and >7:1 selectivity (over double hydrophosphination).

引用

页码：9090 / 9095

页数：6

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