Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands

被引：9
|
作者：
Zhang, Yu [1 ]
Wang, Xinxin [1 ]
Wang, Yaorong [1 ]
Yuan, Dan [1 ]
Yao, Yingming [1 ]
机构：
[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Dushu Lake Campus, Suzhou 215123, Peoples R China
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 27期
基金：
中国国家自然科学基金;
关键词：
RING-OPENING POLYMERIZATION; AMINE BIS(PHENOLATE) LIGANDS; INTERMOLECULAR HYDROPHOSPHINATION; HYDROAMINATION REACTIONS; 1-HEXENE POLYMERIZATION; ALKALINE-EARTHS; RAC-LACTIDE; PRECATALYSTS; REACTIVITY; TITANIUM;
D O I：
10.1039/c8dt02122h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Zirconium complexes stabilized by amine-bridged bis(phenolato) ligands showed good activity and chemo-selectivity in catalyzing intermolecular hydrophosphination of C-C multiple bonds with primary phosphines under mild conditions. A broad range of alkenes and alkynes underwent a mono-addition reaction with phenylphosphine, which generated secondary phosphines in 39-99% yields and >7:1 selectivity (over double hydrophosphination).
引用
收藏
页码：9090 / 9095
页数：6
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