Complex formation of rhodium(III), iridium(III), ruthenium(II), and osmium(II) with germanium(II) in aqueous solutions of hydrofluoric acid

被引：0

作者：

Antonov, PG ^{[1
]}

Lizogub, TN ^{[1
]}

Agapov, IA ^{[1
]}

Manasevich, DS ^{[1
]}

机构：

[1] St Petersburg Technol Inst, St Petersburg, Russia

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 1998年 / 71卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Complex formation of platinum metals with GeF3- ligands in HF aqueous solutions was studied by spectrophotometry. The positions of germanium-to-metal charge-transfer bands in the electronic spectra of Me-Ge complexes were determined. Substitution of GeF3- ions for ammine, thiourea, and SnF3- ligands in Me-Ge compounds was studied. Procedures for the synthesis of Me-Ge complexes were developed. Distinctions in the electronic properties of GeF3- and SnF3- ligands were discussed.

引用

页码：1099 / 1103

页数：5

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