Complex formation of rhodium(III), iridium(III), ruthenium(II), and osmium(II) with germanium(II) in aqueous solutions of hydrofluoric acid

被引：0

作者：

Antonov, PG ^{[1
]}

Lizogub, TN ^{[1
]}

Agapov, IA ^{[1
]}

Manasevich, DS ^{[1
]}

机构：

[1] St Petersburg Technol Inst, St Petersburg, Russia

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 1998年 / 71卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Complex formation of platinum metals with GeF3- ligands in HF aqueous solutions was studied by spectrophotometry. The positions of germanium-to-metal charge-transfer bands in the electronic spectra of Me-Ge complexes were determined. Substitution of GeF3- ions for ammine, thiourea, and SnF3- ligands in Me-Ge compounds was studied. Procedures for the synthesis of Me-Ge complexes were developed. Distinctions in the electronic properties of GeF3- and SnF3- ligands were discussed.

引用

页码：1099 / 1103

页数：5

共 50 条

[31] Complexation of iridium(III) with tin(II) compounds in aqueous solutions of hydrobromic acid
Antonov, PG
Shkredov, VF
Agapov, IA
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 1998, 71 (12) : 2095 - 2099
[32] Complexation of iridium(III) with tin(II) compounds in aqueous solutions of hydrobromic acid
St. Petersburg State Technological Institute, St. Petersburg, Russia
Russ. J. Appl. Chem., 12 (2095-2099):
[33] COMPLEXATION OF IRIDIUM(III) WITH TIN(II) IN AQUEOUS LACTIC-ACID SOLUTIONS
ANTONOV, PG
EMELYANOVA, EN
JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1991, 64 (11): : 2126 - 2129
[34] Mixed-Ligand Complexes of Palladium (II), Ruthenium (II), Rhodium (III) and Iridium (III) with Triphenyl Phosphine and Dibenzyl Sulphide
Pandey, R. N.
Shahi, Kalpana
ORIENTAL JOURNAL OF CHEMISTRY, 2011, 27 (01) : 203 - 208
[35] EXTRACTION PHOTOMETRIC DETERMINATION OF RUTHENIUM(III) IN PRESENCE OF PALLADIUM(II), PLATINUM(II), RHODIUM(III), AND IRIDIUM(III) BY MEANS OF ITS REACTION WITH ISONITROSOACETOPHENONE
SAVOSTINA, VM
SHPIGUN, OA
KLIMOVA, NV
PESHKOVA, VM
JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1977, 32 (08): : 1251 - 1253
[36] INTERACTION OF RHODIUM(II, II) AND RUTHENIUM(II, III) SULFATO COMPLEXES WITH PYRIDAZINE
ZHILYAEV, AN
KUZMENKO, IV
FOMINA, TA
KUZNETSOVA, GN
BARANOVSKII, IB
ZHURNAL NEORGANICHESKOI KHIMII, 1991, 36 (11): : 2796 - 2806
[37] ARE OCTAHEDRAL RUTHENIUM(II/III) AND OSMIUM(II/III) COMPLEXES ALWAYS LOW-SPIN?
Srnec, Martin
Chalupsky, Jakub
Rulisek, Lubomir
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2008, 73 (10) : 1231 - 1244
[38] LUMINESCENT OSMIUM(II) AND IRIDIUM(III) COMPLEXES AS PHOTOSENSITIZERS
DEMAS, JN
HARRIS, EW
FLYNN, CM
DIEMENTE, D
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (13) : 3838 - 3839
[39] STATE OF PALLADIUM(II), RHODIUM(III) AND RUTHENIUM(IV) IN PERCHLORATE SOLUTIONS
ALIMARIN, IP
SHLENSKA.VI
BIRYUKOV, AA
EFREMENK.OA
KHVOSTOV.VP
ZHURNAL ANALITICHESKOI KHIMII, 1970, 25 (10): : 1965 - &
[40] THE SYNTHESIS AND CHARACTERIZATION OF DITHIOURACIL COMPLEXES OF RHODIUM(III), IRIDIUM(III), PALLADIUM(II) AND PLATINUM(II)
LUSTY, JR
CHAN, HSO
PEELING, J
TRANSITION METAL CHEMISTRY, 1983, 8 (06) : 343 - 345

← 1 2 3 4 5 →