Synthesis and characterization of trimetallic ruthenium and bimetallic osmium complexes with metal-vinyl linkages

被引：52
|
作者：
Xia, HP
Wen, TB
Hu, QY
Wang, X
Chen, XG
Shek, LY
Williams, ID
Wong, KS
Wong, GKL
Jia, GC
机构：
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
[2] Hong Kong Univ Sci & Technol, Open Lab Chirotechnol, Inst Mol Technol Drug Discovery & Synth, Kowloon, Hong Kong, Peoples R China
[3] Hong Kong Univ Sci & Technol, Dept Phys, Kowloon, Hong Kong, Peoples R China
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 04期
关键词：
D O I：
10.1021/om0496939
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of RuHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3, which reacts with PMe3 to give 1,3,5-[Cl(CO)(PMe3)(3)RuCH=CH](3)C6H3. 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3 also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh3)(2)RuCH=CH](3)C6H3 (L = Py, PhPy). Reactions of OsHCl(CO)(PPh3)(3) with ArCdropCH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh3)(3). Reaction of OsHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HCdropC-3,5-[Cl(CO)(PPh3)(3)OsCH=CH](2)C6H3, which reacts with PMe3 to give 1-HCdropC-3,5-[OsCl(CO)(PPh3)(2)(PMe3)OsCH=CH](2)C6H3. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.
引用
收藏
页码：562 / 569
页数：8
相关论文
共 50 条
  • [41] Bimetallic Ruthenium Complexes: Synthesis, Characterization, and the Effect of Appending Long Carbon Chains to Their Bridges
    Wu, Xiang-Hua
    Liang, Jin Hua
    Xia, Jian-Long
    Jin, Shan
    Yu, Guang-Ao
    Liu, Sheng Hua
    ORGANOMETALLICS, 2010, 29 (05) : 1150 - 1156
  • [42] Synthesis, characterization and photophysics of alkyne bridged bimetallic rhenium(I) and ruthenium(II) complexes
    Velayudham, Murugesan
    Singaravadivel, Subramanian
    Rajagopal, Seenivasan
    Ramamurthy, Perumal
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (25) : 4076 - 4083
  • [43] Synthesis and characterization of ruthenium-osmium complexes containing μ-bisalkenyl, μ-alkenylvinylidene, and μ-alkenylcarbene bridge ligands
    Buil, ML
    Esteruelas, MA
    ORGANOMETALLICS, 1999, 18 (09) : 1798 - 1800
  • [44] Synthesis and reactivity of coordinatively unsaturated osmium and ruthenium stannyl complexes
    Craig, PR
    Flower, KR
    Roper, WR
    Wright, LJ
    INORGANICA CHIMICA ACTA, 1995, 240 (1-2) : 385 - 391
  • [45] Synthesis and structural characterization of bimetallic ruthenium-nickel carbido and ruthenium-germanium carbonyl cluster complexes
    Saha, Sumit
    Captain, Burjor
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [46] SYNTHESIS, STRUCTURE, AND REACTIVITY PROPERTIES OF DITHIOCARBAMATO COMPLEXES OF RUTHENIUM AND OSMIUM
    PIGNOLET, LH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 179 (MAR): : 41 - INOR
  • [47] Synthesis and characterization of bimetallic trinuclear early/late transition metal complexes
    Bartholomew, Amymarie K.
    Betley, Theodore A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [48] Synthesis and photochemical behavior of binuclear heterometallic complexes of ruthenium and osmium
    Dementev, IA
    Ershov, AY
    Veletskii, NI
    Nikolskii, AB
    ZHURNAL OBSHCHEI KHIMII, 1996, 66 (10): : 1593 - 1596
  • [49] SYNTHESIS AND CHARACTERIZATION OF SOME BIMETALLIC, TRIMETALLIC AND TETRAMETALLIC ALKOXIDES OF IRON(III)
    GUPTA, R
    SHAH, A
    SINGH, A
    MEHROTRA, RC
    NEW JOURNAL OF CHEMISTRY, 1991, 15 (8-9) : 665 - 669
  • [50] Synthesis and characterisation of enynyl, vinyl and acetylide complexes of osmium(II)
    J Parallel Distrib Comput, 2 (719):
12345