Synthesis and characterization of trimetallic ruthenium and bimetallic osmium complexes with metal-vinyl linkages

被引：52
|
作者：
Xia, HP
Wen, TB
Hu, QY
Wang, X
Chen, XG
Shek, LY
Williams, ID
Wong, KS
Wong, GKL
Jia, GC
机构：
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
[2] Hong Kong Univ Sci & Technol, Open Lab Chirotechnol, Inst Mol Technol Drug Discovery & Synth, Kowloon, Hong Kong, Peoples R China
[3] Hong Kong Univ Sci & Technol, Dept Phys, Kowloon, Hong Kong, Peoples R China
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 04期
关键词：
D O I：
10.1021/om0496939
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of RuHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3, which reacts with PMe3 to give 1,3,5-[Cl(CO)(PMe3)(3)RuCH=CH](3)C6H3. 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3 also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh3)(2)RuCH=CH](3)C6H3 (L = Py, PhPy). Reactions of OsHCl(CO)(PPh3)(3) with ArCdropCH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh3)(3). Reaction of OsHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HCdropC-3,5-[Cl(CO)(PPh3)(3)OsCH=CH](2)C6H3, which reacts with PMe3 to give 1-HCdropC-3,5-[OsCl(CO)(PPh3)(2)(PMe3)OsCH=CH](2)C6H3. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.
引用
收藏
页码：562 / 569
页数：8
相关论文
共 50 条
  • [31] MIXED-METAL CLUSTER COMPLEXES OF NICKEL WITH RUTHENIUM OR WITH OSMIUM
    BERGOUNHOU, C
    BONNET, JJ
    LAVIGNE, G
    PAPAGEORGIOU, F
    SHORE, SG
    SIRIWARDANE, U
    INORGANIC SYNTHESES, 1989, 26 : 360 - 365
  • [32] Synthesis and characterization of trimetallic complexes with a borazine core
    Hu, QY
    Lo, MF
    Williams, ID
    Koda, N
    Uchimaru, Y
    Jia, GC
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 670 (1-2) : 243 - 247
  • [33] Bimetallic and trimetallic chains of Fe-CN-Ln complexes: Synthesis, structural characterization, and magnetic properties
    Liu, Yashu
    Chen, Chao
    Dong, Rongyao
    Wu, Kang
    Zhou, Hongbo
    Shen, Xiaoping
    Chen, Shaowei
    INORGANICA CHIMICA ACTA, 2021, 516
  • [34] Synthesis and Characterization of Dibenzoheterocycle-Bridged Dinuclear Ruthenium Alkynyl and Vinyl Complexes
    Zhang, Jing
    Ou, Yaping
    Xu, Meng
    Sun, Chaofang
    Yin, Jun
    Yu, Guang-Ao
    Liu, Sheng Hua
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (18) : 2941 - 2951
  • [35] SULFUR DIOXIDE INSERTION .15. TRANSITION METAL-VINYL COMPLEXES CONTAINING A SULTINE RING
    THOMASSON, JE
    ROBINSON, PW
    ROSS, DA
    WOJCICKI, A
    INORGANIC CHEMISTRY, 1971, 10 (10) : 2130 - +
  • [36] Efficient synthesis of ruthenium vinyl carbene complexes
    Powala, Beata
    Kubicki, Maciej
    Spolnik, Grzegorz
    Danikiewicz, Witold
    Pietraszuk, Cezary
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 752 : 109 - 114
  • [37] SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF NEW RUTHENIUM AND OSMIUM N2O2 COMPLEXES
    MULLER, JG
    TAKEUCHI, KJ
    INORGANIC CHEMISTRY, 1987, 26 (21) : 3634 - 3636
  • [38] Synthesis and characterization of C10H10-bridged bimetallic ruthenium complexes
    Liu, SH
    Hu, QY
    Xue, P
    Wen, TB
    Williams, ID
    Jia, GC
    ORGANOMETALLICS, 2005, 24 (04) : 769 - 772
  • [39] Synthesis and characterization of bimetallic ruthenium complexes connected through linear (CH)14 chain
    Yuan, Ping
    Wu, Xiang-hua
    Yu, Guang-ao
    Du, Dan
    Liu, Sheng Hua
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (16) : 3588 - 3592
  • [40] Synthesis and characterization of cyano bridged ruthenium(II)-with Cd, Hg, and Co bimetallic complexes
    Santiago, MaryAnne Domingo
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
12345