New Pincer-Type Platinum (II) Complexes with 1,3-bis((diphenyl)phosphinoxy)phenyl Ligand. Synthesis, Structure and Electrochemical Properties

被引：1
|
作者：
Verpekin, Victor V. [1 ]
Chudin, Oleg S. [1 ]
Burmakina, Galina, V [1 ]
Kondrasenko, Alexander A. [1 ]
Zimonin, Dmitry, V [1 ,2 ]
Peterson, Ivan, V [1 ]
机构：
[1] Krasnoyarsk Sci Ctr SB RAS, Fed Res Ctr, Inst Chem & Chem Technol SB RAS, Krasnoyarsk, Russia
[2] Siberian Fed Univ, Krasnoyarsk, Russia
来源：
JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2022年 / 15卷 / 02期
关键词：
platinum; pincer ligands; alkynyl ligands; benzothiadiazole; electrochemistry; ALKYNYL COMPLEXES; METALS;
D O I：
10.17516/1998-2836-0290
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of 1,3-bis((diphenyl)phosphinoxy)benzene and PtCl2(L)(2) (L = SMe2, OSMe2, C5H5N) gave the new pincer-type 1,3-bis((diphenyl)phosphinoxy)phenyl platinum (II) complex [eta 3-kappa P:kappa C:kappa P-C6H3-1,3-(OPPh2)(2)]PtCl (1). The reaction between compound 1 and 4-ethynl-2,1,3benzothiadiazole in the presence of copper iodide lead to the new complex [C6H3-1,3-(OPPh2)(2)]Pt-CC(4-C6H3N2S) (2) containing a terminal (4-benzothiadiazol-2,1,3-yDethynyl ligand. The compounds were characterized by IR- and NMR-spectroscopy. These spectroscopy data allow us to propose the molecular structures of 1 and 2. The electrochemical properties of the new complexes were studied, the outcomes of their redox-reactions were proposed.
引用
收藏
页码：251 / 264
页数：14
相关论文
共 50 条
  • [1] Synthesis of unsaturated ruthenium(II) complexes with the new PNP pincer type ligand.
    Ozerov, OV
    Celenligil-Cetin, R
    Guo, CY
    Foxman, BM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U878 - U878
  • [2] Pincer-type bis(carbene)-derived complexes of nickel(II): Synthesis, structure, and catalytic activity
    Inamoto, Kiyofumi
    Kuroda, Jun-ichi
    Kwon, Eunsang
    Hiroya, Kou
    Doi, Takayuki
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (03) : 389 - 396
  • [3] Syntheses, Structures, and Electronic and Optical Properties of Platinum(II) Complexes of 1,3-Bis(imino)benzene-Derived Pincer Ligands
    Blackburn, Octavia A.
    Coe, Benjamin J.
    Helliwell, Madeleine
    Raftery, James
    ORGANOMETALLICS, 2012, 31 (15) : 5307 - 5320
  • [4] Neutral and Cationic NCN Pincer Platinum(II) Complexes with 1,3-Bis(benzimidazol-2′-yl)benzene Ligands: Synthesis, Structures, and Their Photophysical Properties
    Wang, Zhao
    Sun, Zheming
    Hao, Xin-Qi
    Niu, Jun-Long
    Wei, Donghui
    Tu, Tao
    Gong, Jun-Fang
    Song, Mao-Ping
    ORGANOMETALLICS, 2014, 33 (07) : 1563 - 1573
  • [5] Photophysical and electrochemical properties of 1,3-bis(2-pyridylimino)isoindolate platinum(II) derivatives
    Hanson, Kenneth
    Roskop, Luke
    Patel, Niral
    Griffe, Laurent
    Djurovich, Peter I.
    Gordon, Mark S.
    Thompson, Mark E.
    DALTON TRANSACTIONS, 2012, 41 (28) : 8648 - 8659
  • [6] Synthesis, Molecular and Supramolecular Structures of New Cd(II) Pincer-Type Complexes with s-Triazine Core Ligand
    Soliman, Saied M.
    Almarhoon, Zainab
    El-Faham, Ayman
    CRYSTALS, 2019, 9 (05)
  • [7] Synthesis, structure and electrochemical behaviour of Ru(II)- and Pt(II)-carbene complexes of the NCN-pincer 1,3-bis(2-pyridylmethyl)-1H-benzimidazolium chloride
    Das Adhikary, Sirsendu
    Samanta, Tapastaru
    Roymahapatra, Gourisankar
    Loiseau, Frederique
    Jouvenot, Damien
    Giri, Santanab
    Chattaraj, Pratim K.
    Dinda, Joydev
    NEW JOURNAL OF CHEMISTRY, 2010, 34 (09) : 1974 - 1980
  • [8] Neutral and cationic chiral NCN pincer nickel(II) complexes with 1,3-bis(2'-imidazolinyl) benzenes: synthesis and characterization
    Shao, Dan-Dan
    Niu, Jun-Long
    Hao, Xin-Qi
    Gong, Jun-Fang
    Song, Mao-Ping
    DALTON TRANSACTIONS, 2011, 40 (35) : 9012 - 9019
  • [9] SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMICAL PROPERTIES OF AZIDO PALLADIUM AND PLATINUM(I, II) COMPLEXES WITH BIS(DIPHENYLPHOSPHINO)METHANE LIGAND
    KIM, YJ
    CHOI, JC
    PARK, KH
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1994, 15 (08) : 690 - 692
  • [10] Photoluminescent properties of heteroleptic cyclometalated platinum(II) complexes bearing 1,3-bis(3,4-dibutoxyphenyl)propane-1,3-dionate as an ancillary ligand
    Tsujimoto, Hidetaka
    Yagi, Shigeyuki
    Honda, Yuichiro
    Terao, Hiroto
    Maeda, Takeshi
    Nakazumi, Hiroyuki
    Sakurai, Yoshiaki
    JOURNAL OF LUMINESCENCE, 2010, 130 (02) : 217 - 221
12345