Pressure and Thermally Induced Spin Crossover in a 2D Iron(II) Coordination Polymer {Fe[bipy(ttr)2]}n

被引：0

作者：

Yuan, Mengyun ^{[1
]}

Li, Ruixin ^{[1
]}

Li, Quanjun ^{[1
]}

Berezhnaya, Ludmila ^{[2
]}

Fylymonov, Hennagii ^{[3
]}

Seredyuk, Maksym ^{[4
]}

Liedienov, Nikita ^{[1
,5
]}

Real, Jose Antonio ^{[4
]}

Levchenko, Georgiy ^{[1
,5
]}

机构：

[1] Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China

[2] Donetsk Inst Phys & Engn, UA-83114 Donestk, Ukraine

[3] Southern Fed Univ, Rostov Na Donu 344090, Russia

[4] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol, E-46980 Valencia, Spain

[5] NANU, Donetsk Phys Tech Inst, UA-03028 Kiev, Ukraine

来源：

2021 5TH IEEE ELECTRON DEVICES TECHNOLOGY & MANUFACTURING CONFERENCE (EDTM) | 2021年

关键词：

spin crossover; magnetic measurement and visible spectroscopy; PHASE-TRANSITION;

D O I：

10.1109/EDTM50988.2021.9420970

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Using magnetic measurements and UV-visible spectroscopy we have studied the pressure influence on the spin crossover (SCO) properties of the 2D Fe (II) coordination polymer formulated {Fe[bipy(ttr)(2)]}(n). At variable temperature and fixed pressure, we have measured the magnetic property of this compound. Under different pressures and at room temperature, the visible spectroscopy has been observed. The magnetic experiment displays a two-step spin crossover behavior under pressure. The visible spectroscopic measurements at room temperature show a spin crossover with an asymmetric hysteresis at 0.4GPa.

引用

页数：3

共 50 条

[41] Two Mononuclear Iron(II) Spin-Crossover Complexes with a N4O2 Coordination Sphere
Zhang, Li
Xu, Guan-Cheng
Wang, Zhe-Ming
Gao, Song
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (5-6) : 1043 - 1048
[42] Synthesis and characterization of a novel 2D zinc(II) coordination polymer
Li, Xiu-Zhi
Qu, Zhi-Rong
INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (02) : 220 - 222
[43] Synthesis, crystal structure, luminescence property of 2D coordination polymer [Mn(2,4-DAA)2(4,4′-bipy)]n
Yang Ying-Qun
Li Chang-Hong
Li Wei
Mang Shao-Hua
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (09) : 1531 - 1534
[44] Investigation of two 2D interpenetration iron(II) coordination polymers
Luo, Yang-Hui
Qian, Dong-Er
Zhang, Ya-Wen
Jiang, Ye-Hao
Wu, Hong-Shuai
Sun, Bai-Wang
POLYHEDRON, 2016, 110 : 241 - 246
[45] Thermochromic and magnetic properties in a 2D manganese(II) coordination polymer: [MnCl2(bpyO2)]n
Gao, Chenxiu
Zhang, Xu
Liang, Weidong
Zhou, Shouyong
Zhang, Ran
Mao, Yujie
Li, Meisheng
Pang, Aiying
INORGANIC CHEMISTRY COMMUNICATIONS, 2023, 155
[46] Synthesis and crystal structure of [Pb(phe)2]n:: a 2D coordination polymer of lead(II) containing phenylalanine
Marandi, Farzin
Shahbakhsh, Nahid
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (08): : 1137 - 1139
[47] A ladder-type iron(II) coordination polymer with enhanced spin-crossover behavior
Yan, Zheng
Zhu, Long-Feng
Zhu, Lian-Wen
Meng, Yan
Hoque, Md. Najbul
Liu, Jun-Liang
Chen, Yan-Cong
Ni, Zhao-Ping
Tong, Ming-Liang
INORGANIC CHEMISTRY FRONTIERS, 2017, 4 (06): : 921 - 926
[48] Switchable nanoparticles based on Fe(II)-Au(I) spin-crossover coordination polymer
Bibik, Yurii S.
Fritsky, Igor O.
Kucheriv, Olesia I.
Marynin, Andriy I.
Molnar, Gabor
Salmon, Lionel
Bousseksou, Azzedine
Gural'skiy, Il'ya A.
JOURNAL OF MOLECULAR STRUCTURE, 2024, 1318
[49] Influence of conformational changes on spin crossover properties and superstructure formation in 2D coordination polymers [Fe(hbtz)2(RCN)2](ClO4)2
Ksiazek, Maria
Kusz, Joachim
Bialonska, Agata
Bronisz, Robert
Weselski, Marek
DALTON TRANSACTIONS, 2015, 44 (42) : 18563 - 18575
[50] Spin crossover (SCO) iron(II) coordination polymer chain: Synthesis, structural and magnetic characterizations of [Fe(abpt)2(μ-M(CN)4)] (M = PtII and NiII)
Setifi, Fatima
Charles, Catherine
Houille, Sylvie
Thetiot, Franck
Triki, Smail
Gomez-Garcia, Carlos J.
Pillet, Sebastien
POLYHEDRON, 2013, 61 : 242 - 247

← 1 2 3 4 5 →