Pressure and Thermally Induced Spin Crossover in a 2D Iron(II) Coordination Polymer {Fe[bipy(ttr)2]}n

被引：0
|
作者：
Yuan, Mengyun [1 ]
Li, Ruixin [1 ]
Li, Quanjun [1 ]
Berezhnaya, Ludmila [2 ]
Fylymonov, Hennagii [3 ]
Seredyuk, Maksym [4 ]
Liedienov, Nikita [1 ,5 ]
Real, Jose Antonio [4 ]
Levchenko, Georgiy [1 ,5 ]
机构：
[1] Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China
[2] Donetsk Inst Phys & Engn, UA-83114 Donestk, Ukraine
[3] Southern Fed Univ, Rostov Na Donu 344090, Russia
[4] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol, E-46980 Valencia, Spain
[5] NANU, Donetsk Phys Tech Inst, UA-03028 Kiev, Ukraine
来源：
2021 5TH IEEE ELECTRON DEVICES TECHNOLOGY & MANUFACTURING CONFERENCE (EDTM) | 2021年
关键词：
spin crossover; magnetic measurement and visible spectroscopy; PHASE-TRANSITION;
D O I：
10.1109/EDTM50988.2021.9420970
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
Using magnetic measurements and UV-visible spectroscopy we have studied the pressure influence on the spin crossover (SCO) properties of the 2D Fe (II) coordination polymer formulated {Fe[bipy(ttr)(2)]}(n). At variable temperature and fixed pressure, we have measured the magnetic property of this compound. Under different pressures and at room temperature, the visible spectroscopy has been observed. The magnetic experiment displays a two-step spin crossover behavior under pressure. The visible spectroscopic measurements at room temperature show a spin crossover with an asymmetric hysteresis at 0.4GPa.
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页数：3
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