Air-Stable, Room-Temperature Emissive Disilenes with π-Extended Aromatic Groups

被引：48

作者：

Kobayashi, Megumi ^{[1
]}

Matsuo, Tsukasa ^{[1
]}

Fukunaga, Takeo ^{[2
]}

Hashizume, Daisuke ^{[2
]}

Fueno, Hiroyuki ^{[3
]}

Tanaka, Kazuyoshi ^{[3
]}

Tamao, Kohei ^{[1
]}

机构：

[1] RIKEN, Adv Sci Inst, Funct Elementoorgan Chem Unit, Saitama 3510198, Japan

[2] RIKEN, Adv Sci Inst, Adv Technol Support Div, Saitama 3510198, Japan

[3] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 43期

关键词：

COMPOUND; CHEMISTRY; BONDS;

D O I：

10.1021/ja108094m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

pi-Conjugated disilenes with 2-naphthyl or 2-fluorenyl groups on the silicon atoms have been synthesized as air-stable emissive red solids using the bulky 1,1,3,3,5,5,7,7-octaethyl-s-hydrindacen-4-yl (Eind) groups. The strong a pi-pi* absorptions and distinct emission at room temperature, both in solution and in the solid state, have been observed due to the substantial contribution of the 3p(pi)*(Si-Si)-2p(pi)*(carbon pi-electron system) conjugation.

引用

页码：15162 / 15163

页数：2

共 50 条

[41] Room-Temperature Synthesis of Air-Stable and Size-Tunable Luminescent ZnS-Coated Cd3P2 Nanocrystals with High Quantum Yields
Ojo, Wilfried-Solo
Xu, Shu
Delpech, Fabien
Nayral, Celine
Chaudret, Bruno
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (03) : 738 - 741
[42] An Amphoteric Switch to Aromatic and Antiaromatic States of a Neutral Air-Stable 25π Radical
Gopalakrishna, Tullimilli Y.
Reddy, J. Sreedhar
Anand, Venkataramanarao G.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (41) : 10984 - 10987
[43] Bistetracene: An Air-Stable, High-Mobility Organic Semiconductor with Extended Conjugation
Zhang, Lei
Fonari, Alexandr
Liu, Yao
Hoyt, Andra-Lisa M.
Lee, Hyunbok
Granger, Devin
Parkin, Sean
Russell, Thomas P.
Anthony, John E.
Bredas, Jean-Luc
Coropceanu, Veaceslav
Briseno, Alejandro L.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (26) : 9248 - 9251
[44] Study on a Room-Temperature Air Plasma for Biomedical Application
Wu, ShuQun
Wang, Zhan
Huang, QuanJun
Lu, XinPei
Pan, Yuan
IEEE TRANSACTIONS ON PLASMA SCIENCE, 2011, 39 (06) : 1489 - 1495
[45] ROOM-TEMPERATURE PHOSPHORESCENCE OF POLYNUCLEAR AROMATIC-HYDROCARBONS IN CYCLODEXTRINS
SCYPINSKI, S
LOVE, LJC
ANALYTICAL CHEMISTRY, 1984, 56 (03) : 322 - 327
[46] Green synthesis: Aromatic nitrations in room-temperature ionic liquids
Handy, ST
Egrie, CR
IONIC LIQUIDS: INDUSTRIAL APPLICATIONS FOR GREEN CHEMISTRY, 2002, 818 : 134 - 146
[47] ROOM-TEMPERATURE FLUORINATION OF AROMATIC-MOLECULES WITH CESIUM FLUOROXYSULFATE
STAVBER, S
ZUPAN, M
JOURNAL OF FLUORINE CHEMISTRY, 1981, 17 (06) : 597 - 600
[48] HYDROPYROLYSIS OF COAL - OXIDATION OF COAL IN AIR AT ROOM-TEMPERATURE
DYLA, P
ERDOL & KOHLE ERDGAS PETROCHEMIE, 1991, 44 (06): : 239 - 243
[49] Green Synthesis: Aromatic Nitrations in Room-Temperature Ionic Liquids
Handy, Scott T.
Egrie, Cristina R.
2002, Oxford University Press (818): : 134 - 146
[50] ELECTROCHEMISTRY OF AROMATIC KETONES IN A ROOM-TEMPERATURE MOLTEN-SALT
CHEEK, GT
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 94 - ANYL

← 1 2 3 4 5 →