Green Synthesis: Aromatic Nitrations in Room-Temperature Ionic Liquids

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作者
Handy, Scott T. [1 ]
Egrie, Cristina R. [1 ]
机构
[1] Department of Chemistry, State Univ. New York at Binghamton, Binghamton, NY 13902, United States
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| 2002年 / Oxford University Press卷 / 818期
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摘要
As one of the least environmentally compatible synthetic methods, aromatic nitration has attracted a great deal of effort in terms of the design of more benign techniques. Room temperature ionic liquids (RTILs) afford a useful new method for aromatic nitration by using a simple nitrating agent (nitric acid) with a transition metal catalyst. Distillation of the nitration products affords a solvent/catalyst system that can be readily recycled for at least 4 reactions.
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页码:134 / 146
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