Synthesis and x-ray structure of p-tolyl phenylthioglyoxylate

被引：5
|
作者：
Boryczka, S
Glowiak, T
LeGuillanton, G
Do, QT
Elothmani, D
机构：
[1] UNIV WROCLAW,INST CHEM,PL-50383 WROCLAW,POLAND
[2] UNIV CATHOLIQUE OUEST,LAB ELECTROCHIM ORGAN,CNRS,F-49008 ANGERS 01,FRANCE
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1996年 / 26卷 / 03期
关键词：
alpha-oxo-thioester; thioglyoxylate;
D O I：
10.1007/BF01673677
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound (C15H12O2S) is triclinic with a = 7.077(10), b = 8.825(2), c = 11.068(2) Angstrom, beta = 106.66(3)degrees, Z = 2, and space group P (1) over bar. The significant structural features lies in the two carbonyl groups of the thioglyoxylate which are oriented antiperiplanar to each other [-168.2(2)degrees] The central C(8)-C(9) bond is 1.553(3) Angstrom. The phenyl rings are twisted with respect to the carbonyl groups. Short contacts are present between S and O(1) [2.652(2) Angstrom] and also between S and O(2) [2.758(2) Angstrom].
引用
收藏
页码：231 / 234
页数：4
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