Synthesis and x-ray structure of p-tolyl phenylthioglyoxylate

被引：5
|
作者：
Boryczka, S
Glowiak, T
LeGuillanton, G
Do, QT
Elothmani, D
机构：
[1] UNIV WROCLAW,INST CHEM,PL-50383 WROCLAW,POLAND
[2] UNIV CATHOLIQUE OUEST,LAB ELECTROCHIM ORGAN,CNRS,F-49008 ANGERS 01,FRANCE
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1996年 / 26卷 / 03期
关键词：
alpha-oxo-thioester; thioglyoxylate;
D O I：
10.1007/BF01673677
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound (C15H12O2S) is triclinic with a = 7.077(10), b = 8.825(2), c = 11.068(2) Angstrom, beta = 106.66(3)degrees, Z = 2, and space group P (1) over bar. The significant structural features lies in the two carbonyl groups of the thioglyoxylate which are oriented antiperiplanar to each other [-168.2(2)degrees] The central C(8)-C(9) bond is 1.553(3) Angstrom. The phenyl rings are twisted with respect to the carbonyl groups. Short contacts are present between S and O(1) [2.652(2) Angstrom] and also between S and O(2) [2.758(2) Angstrom].
引用
收藏
页码：231 / 234
页数：4
相关论文
共 50 条
  • [21] UTILIZATION OF METHYLTHIOMETHYL P-TOLYL SULFONE IN ORGANIC-SYNTHESIS
    OGURA, K
    YAHATA, N
    HASHIZUME, K
    TSUYAMA, K
    TAKAHASHI, K
    IIDA, H
    CHEMISTRY LETTERS, 1983, (05) : 767 - 770
  • [22] Structure of 2-chloro-N-(p-tolyl)propanamide
    Jones, Roderick C.
    Twamley, Brendan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1584 - +
  • [23] Synthesis and purification of P-tolyl porphyrins using dipyrromethane intermediates
    Mullaley, A
    Daggett, KA
    McCullagh, J
    Kerrigan, PK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U645 - U645
  • [24] STRUCTURE OF POLY(P-TOLYL METHACRYLATE) DETERMINED BY IR AND NMR
    GUENIFFEY, H
    KAMMERER, H
    KLESPER, E
    MAKROMOLEKULARE CHEMIE, 1972, 162 (NDEC): : 199 - +
  • [25] An X-ray Crystallographic Study of 1,4-Di[(E)-2-(p-tolyl)-1-diazenyl] piperazine
    Little, Vanessa Renee
    Bertolasi, Valerio
    Vaughan, Keith
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2010, 40 (10) : 807 - 811
  • [26] An X-ray Crystallographic Study of 1,4-Di[(E)-2-(p-tolyl)-1-diazenyl]piperazine
    Vanessa Renee Little
    Valerio Bertolasi
    Keith Vaughan
    Journal of Chemical Crystallography, 2010, 40 : 807 - 811
  • [27] (p-tolyl)dichlorophosphine and di(p-tolyl)chlorophosphine -: Sources of new organophosphorus(III) and (V) compounds
    Fagadar-Cosma, E
    Fagadar-Cosma, G
    REVUE ROUMAINE DE CHIMIE, 2003, 48 (03) : 211 - 217
  • [28] Trifluoromethyl-containing pyrazolinyl (p-tolyl) sulfones:: The synthesis and structure of promising antimicrobial agents
    Bonacorso, Helio G.
    Wentz, Alexandre P.
    Lourega, Rogerio V.
    Cechinel, Cleber A.
    Moraes, Tatiana S.
    Coelho, Helena S.
    Zanatta, Nilo
    Martins, Marcos A. P.
    Hoerner, Manfredo
    Alves, Sydney H.
    JOURNAL OF FLUORINE CHEMISTRY, 2006, 127 (08) : 1066 - 1072
  • [29] Synthesis and crystal and molecular structure of mu-oxo-bis[trifluoroacetato(p-tolyl)iodine]
    Chekhlov, AN
    Kasumov, TM
    Brel, VK
    Zefirov, NS
    JOURNAL OF STRUCTURAL CHEMISTRY, 1996, 37 (05) : 800 - 806
  • [30] The synthesis of P-tolyl and P-anisyl porphyrins for cancer treatment.
    Iniya, M
    Kerrigan, P
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U293 - U293
12345