Recent studies on solid acid catalysis and solid base catalysis for fine chemicals synthesis

被引：2

作者：

Onaka, M ^{[1
]}

Seki, T ^{[1
]}

Masui, Y ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2005年 / 63卷 / 05期

关键词：

solid acid catalysis; solid base catalysis; zeolite; mesoporous aluminosilicate; montmorillonite; hydroxyapatite; alkali-earth metal oxide; supercritical carbon dioxide; finechemicals synthesis;

D O I：

10.5059/yukigoseikyokaishi.63.492

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new type of solid acid and base-catalyzed reactions has been selected and addressed from the viewpoint of practical reactions applicable to fine chemicals synthesis. As solid acid catalysts, zeolites (NaY, Sn-beta, Ti-beta, molecular sieves 4 A (MS 4 A)), mesoporous aluminosilicates (Al-MCM-41, Al-HMS), montmorillonite (Ti-Mont), hydroxyapatite (Ru-HAP), Ru(OH)(x)/Al2O3, and polystyrene-supported sulfonic acid were reviewed in carbonyl-ene reaction, the Diels-Alder reaction, alkylation, aldol-type condensation, oxidation, reduction, hydration, acetalization, and esterification. Solid base catalysis by alkali-earth metal oxide (MgO, CaO, SrO, Mg-Al mixed oxide, KOH/Fe2O3), hydrotalcite (HT-OH, HT-tBuO), and MS 4 A was mainly discussed in the carbon-carbon and carbon-oxygen bond forming reactions.

引用

页码：492 / 502

页数：11

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