SOLVENT EFFECTS IN HETEROGENEOUS CATALYSIS - APPLICATION TO THE SYNTHESIS OF FINE CHEMICALS

被引：0
|
作者：
GILBERT, L
MERCIER, C
机构：
来源：
HETEROGENEOUS CATALYSIS AND FINE CHEMICALS III | 1993年 / 78卷
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暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Solvent effects in heterogeneous catalysis are examined in terms of physical or chemical modifications to control the chemo-, regio- and stereoselectivity of a reaction. The main factors affecting selectivity are reactant solubility, polarity, reactivity or acido-basicity of solvents and competitive chemisorption of products and solvents. In the special case of molecular sieves, selectivity control of a reaction by competitive adsorption, diffusion or shape selectivity and confinement catalysis are also examined.
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页码：51 / 66
页数：16
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