(1S,2S,6S,9S)-6-Methyl-5-oxobicyclo[4.4.0]decane-2,9-diyl diacetate

被引：0

作者：

Aav, Riina ^{[1
]}

Lippur, Kristin ^{[1
]}

Lopp, Margus ^{[1
]}

Werner, Franz ^{[1
]}

机构：

[1] Tallinn Univ Technol, Dept Chem, EE-12618 Tallinn, Estonia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

D O I：

10.1107/S1600536810036639

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The chiral title compound, C15H22O5, is an intermediate in the total synthesis of biologically active 9,11-secosterols. In the crystal, the cyclohexane rings are trans-fused and both adopt chair conformations. In the crystal, molecules are loosely held together in a layer parallel to (100) by weak intermolcular C-H center dot center dot center dot O hydrogen bonds accepted by carbonyl O atoms of the acetyl groups.

引用

页码：O2584 / U669

页数：10

共 50 条

[41] 2-Methylpropan-2-ammonium [(3R,5R)-7-[(1S,2S,6S,8S,8aR)-6-hydroxy-2-methyl-8-[(2S)-2-methylbutanoyl]oxy-1,2,6,7,8,8a-hexahydronaphthalen-1-yl]-3,5-heptanoate
Grosu, Ioana-Georgeta
Turza, Alexandru
Filip, Xenia
Miclaus, Maria-Olimpia
MOLBANK, 2024, 2024 (03)
[42] (-)-(1S,3R,4R,6S)-4,7,7-TRIMETHYL-5-OXOBICYCLO[4.1.0]HEPTANE-3-CARBONITRILE
HIBBS, DE
HURSTHOUSE, MB
MALIK, KMA
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 2315 - 2317
[43] Pheromone synthesis, CXCVIII -: Synthesis of (1S,2S,6S,10R)- and (1S,2R,6R,10R)-1,2,6,10-tetramethyldodecyl propanoate, the components of the sex pheromone of the pine sawfly, Microdiprion pallipes
Nakamura, Y
Mori, K
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 1999, 1999 (09) : 2175 - 2182
[44] Stereoselective synthesis of fully protected (2S,4S,6S)-2-amino-6-hydroxy-4-methyl-8-oxodecanoic acid (AHMOD)
Zhang, Wei
Li, Xiangpeng
Ding, Ning
Li, Yingxia
JOURNAL OF PEPTIDE SCIENCE, 2012, 18 (03) : 163 - 169
[45] METHYL (2S,6S/2R,6R)-6-(2-CYANOETHYL)-4,6-DIMETHYL-2-MORPHOLINEACETATE
SUN, GB
FRONCZEK, FR
GANDOUR, RD
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 980 - 982
[46] Interactions of (2S,6S;2R,6R)-Hydroxynorketamine, a Secondary Metabolite of (R,S)-Ketamine, with Morphine
Lilius, Tuomas O.
Viisanen, Hanna
Jokinen, Viljami
Niemi, Mikko
Kalso, Eija A.
Rauhala, Pekka V.
BASIC & CLINICAL PHARMACOLOGY & TOXICOLOGY, 2018, 122 (05) : 481 - 488
[47] Shake-up transitions in S 2p, S 2s and F 1s photoionization of the SF6 molecule
Decleva, P.
Fronzoni, G.
Kivimaeki, A.
Ruiz, J. Alvarez
Svensson, S.
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2009, 42 (05)
[48] 1S(2) 2S S-2(1/2)-1S2S2P P-4(5/2) AND 1S(2)2S(2) S-1(0)-1S(2)2S2P P-3(2) MAGNETIC QUADRUPOLE TRANSITIONS
LAUGHLIN, C
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1975, 8 (06) : 842 - 851
[49] Diastereoselective synthesis of (1S,2S,3R,6S) 3-chloro-3-methyl-6-isopropenyl-1,2-cyclohexanediol via Prins reaction induced by zinc and trimethylsilyl chloride.
Marty, M
StoeckliEvans, H
Neier, R
TETRAHEDRON, 1996, 52 (13) : 4645 - 4658
[50] Crystal structures of (3S*,4S*,5S*,6S*)-3,4-epoxy-1,7-dioxaspiro[5.5]undecan-5-ol, (3R*,5S*,6S*)-1,7-dioxaspiro[5.5]undecane-3,5-diyl diacetate and(4S*,5S*6S*)-1,7-dioxaspiro[5.5]undecane-4,5-diol
Brimble, MA
Johnston, A
Hambley, TW
Turner, P
AUSTRALIAN JOURNAL OF CHEMISTRY, 1997, 50 (02) : 123 - 127

← 1 2 3 4 5 →