(1S,2S,6S,9S)-6-Methyl-5-oxobicyclo[4.4.0]decane-2,9-diyl diacetate

被引:0
|
作者
Aav, Riina [1 ]
Lippur, Kristin [1 ]
Lopp, Margus [1 ]
Werner, Franz [1 ]
机构
[1] Tallinn Univ Technol, Dept Chem, EE-12618 Tallinn, Estonia
关键词
D O I
10.1107/S1600536810036639
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The chiral title compound, C15H22O5, is an intermediate in the total synthesis of biologically active 9,11-secosterols. In the crystal, the cyclohexane rings are trans-fused and both adopt chair conformations. In the crystal, molecules are loosely held together in a layer parallel to (100) by weak intermolcular C-H center dot center dot center dot O hydrogen bonds accepted by carbonyl O atoms of the acetyl groups.
引用
收藏
页码:O2584 / U669
页数:10
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