Synthesis and Structure of Some Zinc and Cadmium 1,2-Cyclohexanedione Dioximines

被引：2

作者：

Coropceanu, E. ^{[1
,2
]}

Croitor, L. ^{[3
]}

Ciloci, A. ^{[4
]}

Clapco, S. ^{[4
]}

Labliuc, S. ^{[4
]}

Codreanu, S. ^{[2
]}

Fonari, M. ^{[3
]}

机构：

[1] Moldavian Acad Sci, Inst Chem, Kishinev, Moldova

[2] Tiraspol State Univ, Kishinev, Moldova

[3] Moldavian Acad Sci, Inst Appl Phys, Kishinev, Moldova

[4] Moldavian Acad Sci, Inst Microbiol & Biotechnol, Kishinev, Moldova

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2017年 / 43卷 / 07期

关键词：

coordination compounds; crystal structure; d(10)-metals; 1,2-cyclohexanedione dioxime; ONE-DIMENSIONAL ZN(II); LUMINESCENT PROPERTIES; MONONUCLEAR CD(II); CRYSTAL-STRUCTURE; COMPLEXES; LIGAND; COPPER(II); DIOXIMATE; CENTERS;

D O I：

10.1134/S1070328417070053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [Zn(CH3COO)(2)(NioxH(2))(DMF)(H2O)] (I), [Cd(CH3COO)(2)(NioxH(2))(DMF)(H2O)] (II), [Zn(CH3COO)(2)(NioxH(2))(S-Nia)(H2O)] center dot DMF (III), [Zn(CH3COO)(2)(NioxH(2))(Nia)(H2O)] (IV), and [Zn(CH3COO)(2)(NioxH(2))(INia)(H2O)] (V), where NioxH(2) is 1,2-cyclohexanedione dioxime, S-Nia is thionicotinamide, Nia is nicotinamide, and INia is isonicotinamide, were prepared and investigated. Compounds I-III were studied by X-ray diffraction (CCDC nos. 1505280-1505282 for I-III, respectively). Testing of zinc complexes containing various ligands demonstrated that at the optimized concentration (5 mg/L), they can be used for stimulating biosynthesis of both standard (57.14%, pH 4.7) and acid-labile (17.63%, pH 2.5) amylases by the micromycete Aspergillus niger CNMN FD 06 without affecting the duration of producer culturing.

引用

页码：433 / 440

页数：8

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