Synthesis and Structure of Some Zinc and Cadmium 1,2-Cyclohexanedione Dioximines

被引：2
|
作者：
Coropceanu, E. [1 ,2 ]
Croitor, L. [3 ]
Ciloci, A. [4 ]
Clapco, S. [4 ]
Labliuc, S. [4 ]
Codreanu, S. [2 ]
Fonari, M. [3 ]
机构：
[1] Moldavian Acad Sci, Inst Chem, Kishinev, Moldova
[2] Tiraspol State Univ, Kishinev, Moldova
[3] Moldavian Acad Sci, Inst Appl Phys, Kishinev, Moldova
[4] Moldavian Acad Sci, Inst Microbiol & Biotechnol, Kishinev, Moldova
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2017年 / 43卷 / 07期
关键词：
coordination compounds; crystal structure; d(10)-metals; 1,2-cyclohexanedione dioxime; ONE-DIMENSIONAL ZN(II); LUMINESCENT PROPERTIES; MONONUCLEAR CD(II); CRYSTAL-STRUCTURE; COMPLEXES; LIGAND; COPPER(II); DIOXIMATE; CENTERS;
D O I：
10.1134/S1070328417070053
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexes [Zn(CH3COO)(2)(NioxH(2))(DMF)(H2O)] (I), [Cd(CH3COO)(2)(NioxH(2))(DMF)(H2O)] (II), [Zn(CH3COO)(2)(NioxH(2))(S-Nia)(H2O)] center dot DMF (III), [Zn(CH3COO)(2)(NioxH(2))(Nia)(H2O)] (IV), and [Zn(CH3COO)(2)(NioxH(2))(INia)(H2O)] (V), where NioxH(2) is 1,2-cyclohexanedione dioxime, S-Nia is thionicotinamide, Nia is nicotinamide, and INia is isonicotinamide, were prepared and investigated. Compounds I-III were studied by X-ray diffraction (CCDC nos. 1505280-1505282 for I-III, respectively). Testing of zinc complexes containing various ligands demonstrated that at the optimized concentration (5 mg/L), they can be used for stimulating biosynthesis of both standard (57.14%, pH 4.7) and acid-labile (17.63%, pH 2.5) amylases by the micromycete Aspergillus niger CNMN FD 06 without affecting the duration of producer culturing.
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页码：433 / 440
页数：8
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